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  • The diamagnetic-paramagnetic and insulator-metal transitions in perovskites LnCoO3 (Ln=La, Y, rare earths) have been studied systematically. In a thermodynamic model, the transitions are interpreted as a two-step process, where first level are local excitations of Co3+ LS->S and second level is a stabilization of metallic phase with IS Co3+ due to electron transfer between LS/HS pairs.
  • The diamagnetic-paramagnetic and insulator-metal transitions in perovskites LnCoO3 (Ln=La, Y, rare earths) have been studied systematically. In a thermodynamic model, the transitions are interpreted as a two-step process, where first level are local excitations of Co3+ LS->S and second level is a stabilization of metallic phase with IS Co3+ due to electron transfer between LS/HS pairs. (en)
  • Přechody typu diamagnetismus-paramagnetismus a isolátor-kov v perovskitech LnCoO3 (Ln=La, Y, vzácné zeminy) byly systematicky studovány. Termodynamický model interpretuje přechody jako dvojstupňový proces, kde prvním krokem jsou lokální excitace Co3+ LS->HS a druhým krokem stabilizace metalické fáze s IS Co3+ v důsledku elektronového transferu mezi LS/HS páry. (cs)
Title
  • Structural anomalies, spin transitions and charge disproportionation in LnCoO3.
  • Structural anomalies, spin transitions and charge disproportionation in LnCoO3. (en)
  • Strukturní anomalie, spinové přechody a nábojová disproporcionace v LnCoO3. (cs)
skos:prefLabel
  • Structural anomalies, spin transitions and charge disproportionation in LnCoO3.
  • Structural anomalies, spin transitions and charge disproportionation in LnCoO3. (en)
  • Strukturní anomalie, spinové přechody a nábojová disproporcionace v LnCoO3. (cs)
skos:notation
  • RIV/68378271:_____/08:00313199!RIV09-AV0-68378271
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA202/06/0051), Z(AV0Z10100521)
http://linked.open...iv/cisloPeriodika
  • 7
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 397758
http://linked.open...ai/riv/idVysledku
  • RIV/68378271:_____/08:00313199
http://linked.open...riv/jazykVysledku
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  • LnCoO3; neutron diffraction; thermal expansion; spin-state transition (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [8EE058D658E0]
http://linked.open...i/riv/nazevZdroje
  • Journal of Applied Physics
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 103
http://linked.open...iv/tvurceVysledku
  • Knížek, Karel
  • Jirák, Zdeněk
  • Hejtmánek, Jiří
  • André, G.
  • Henry, P.
http://linked.open...ain/vavai/riv/wos
  • 000255043200266
http://linked.open...n/vavai/riv/zamer
issn
  • 0021-8979
number of pages
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