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  • Hydrogen absorption in uranium ternary intermetallic compounds typically increases ordering temperatures and magnetic moments. The case of URuSn hydride, which does not behave accordingly, can be related to specific H positions revealed by neutron diffraction on deuterides. Tuning through the onset of magnetic ordering by means of H absorption was found for the U2T2X compounds as U2Co2Sn. For U2Ni2SnD1.8, we demonstrated that the anisotropic lattice expansion leads to U moments reorientation, as a result of hybridisation-induced two-ion anisotropy, with respect to U2Ni2Sn, in which the U-U coordination is poised between two regimes.
  • Hydrogen absorption in uranium ternary intermetallic compounds typically increases ordering temperatures and magnetic moments. The case of URuSn hydride, which does not behave accordingly, can be related to specific H positions revealed by neutron diffraction on deuterides. Tuning through the onset of magnetic ordering by means of H absorption was found for the U2T2X compounds as U2Co2Sn. For U2Ni2SnD1.8, we demonstrated that the anisotropic lattice expansion leads to U moments reorientation, as a result of hybridisation-induced two-ion anisotropy, with respect to U2Ni2Sn, in which the U-U coordination is poised between two regimes. (en)
Title
  • 5f magnetism studied in complex intermetallic U-base hydrides
  • 5f magnetism studied in complex intermetallic U-base hydrides (en)
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  • 5f magnetism studied in complex intermetallic U-base hydrides
  • 5f magnetism studied in complex intermetallic U-base hydrides (en)
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  • RIV/68378271:_____/07:00342242!RIV11-AV0-68378271
http://linked.open...avai/riv/aktivita
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  • 463357
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  • RIV/68378271:_____/07:00342242
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  • actinide alloys and compounds; hydrogen; magnetisation; heat capacity; neutron diffraction (en)
http://linked.open.../riv/klicoveSlovo
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  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [43E6EE7097C8]
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  • Journal of Alloys and Compounds
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  • 446-447
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  • Šantavá, Eva
  • Havela, L.
  • Prokeš, K.
  • Goncalves, A. P.
  • Pereira, L. C. J.
  • Miliyanchuk, K.
  • Kolomiets, A. V.
http://linked.open...ain/vavai/riv/wos
  • 000250822900130
http://linked.open...n/vavai/riv/zamer
issn
  • 0925-8388
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