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  • Ferrocenestrone, the first steroid derivative containing a metallocene moiety, was stereoselectively prepared (see scheme). The key steps included the enantioselective functionalization of ferrocene, elongation of the side chain, intramolecular enyne metathesis, Diels–Alder reaction, heterogeneous hydrogenation of the sterically hindered double bond, and finally inversion of the configuration at C13.
  • Ferrocenestrone, the first steroid derivative containing a metallocene moiety, was stereoselectively prepared (see scheme). The key steps included the enantioselective functionalization of ferrocene, elongation of the side chain, intramolecular enyne metathesis, Diels–Alder reaction, heterogeneous hydrogenation of the sterically hindered double bond, and finally inversion of the configuration at C13. (en)
Title
  • Synthesis of ferrocenestrone: the first metallocene based steroid analogue
  • Synthesis of ferrocenestrone: the first metallocene based steroid analogue (en)
skos:prefLabel
  • Synthesis of ferrocenestrone: the first metallocene based steroid analogue
  • Synthesis of ferrocenestrone: the first metallocene based steroid analogue (en)
skos:notation
  • RIV/68378050:_____/12:00387886!RIV13-GA0-68378050
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(1M0508), P(GA204/09/1905), P(LC06077), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika
  • 18
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 172961
http://linked.open...ai/riv/idVysledku
  • RIV/68378050:_____/12:00387886
http://linked.open...riv/jazykVysledku
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  • asymmetric synthesis; ferrocenestrones; metallocenes; steroids; synthesis design (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [6B80A65CBD9A]
http://linked.open...i/riv/nazevZdroje
  • Chemistry - A European Journal
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 18
http://linked.open...iv/tvurceVysledku
  • Bartůněk, Petr
  • Císařová, I.
  • Kotora, Martin
  • Sedlák, David
  • Hessler, F.
http://linked.open...ain/vavai/riv/wos
  • 000302991600007
http://linked.open...n/vavai/riv/zamer
issn
  • 0947-6539
number of pages
http://bibframe.org/vocab/doi
  • 10.1002/chem.201200687
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