About: Alloying of Mg/Mg2Ni eutectic by chosen non-hydride forming elements: Relation between segregation of the third element and hydride storage capacity     Goto   Sponge   NotDistinct   Permalink

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  • Eutectic mixture Mg–11.3 at.% Ni was modified by elements X from the 13th (Al, Ga, In) and 14th group (Si, Ge, Sn and Pb). Phase analysis and distribution of X between primary solid solution Mg–Ni–X and Mg2Ni–X compound was carried out in stabilization annealed samples before hydrogen charging and in hydrided state. In the both states, it was found that X prefers Mg2Ni–X to Mg–Ni–X solid solution, and that the preference is stronger in the hydrided state. The effect is more pronounced for elements X from the 13th group. Suggested explanation was based on influence of X on the formation enthalpy of hydrides. It was observed that In increases the hydrogen storage capacity of the eutectic mixture. The most likely explanation is based on a strong segregation of In to phase Mg2Ni–X, and on a weak tendency of In to form phases with Mg and Ni.
  • Eutectic mixture Mg–11.3 at.% Ni was modified by elements X from the 13th (Al, Ga, In) and 14th group (Si, Ge, Sn and Pb). Phase analysis and distribution of X between primary solid solution Mg–Ni–X and Mg2Ni–X compound was carried out in stabilization annealed samples before hydrogen charging and in hydrided state. In the both states, it was found that X prefers Mg2Ni–X to Mg–Ni–X solid solution, and that the preference is stronger in the hydrided state. The effect is more pronounced for elements X from the 13th group. Suggested explanation was based on influence of X on the formation enthalpy of hydrides. It was observed that In increases the hydrogen storage capacity of the eutectic mixture. The most likely explanation is based on a strong segregation of In to phase Mg2Ni–X, and on a weak tendency of In to form phases with Mg and Ni. (en)
Title
  • Alloying of Mg/Mg2Ni eutectic by chosen non-hydride forming elements: Relation between segregation of the third element and hydride storage capacity
  • Alloying of Mg/Mg2Ni eutectic by chosen non-hydride forming elements: Relation between segregation of the third element and hydride storage capacity (en)
skos:prefLabel
  • Alloying of Mg/Mg2Ni eutectic by chosen non-hydride forming elements: Relation between segregation of the third element and hydride storage capacity
  • Alloying of Mg/Mg2Ni eutectic by chosen non-hydride forming elements: Relation between segregation of the third element and hydride storage capacity (en)
skos:notation
  • RIV/68081723:_____/12:00369591!RIV12-AV0-68081723
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA106/09/0814), P(GAP108/11/0148), Z(AV0Z20410507)
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  • 1
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  • 121710
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  • RIV/68081723:_____/12:00369591
http://linked.open...riv/jazykVysledku
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  • Energy storage materials; Hydrogen storage capacity; Metal hydrides (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [19D8C54974AE]
http://linked.open...i/riv/nazevZdroje
  • Journal of Power Sources
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http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...v/svazekPeriodika
  • 197
http://linked.open...iv/tvurceVysledku
  • Král, Lubomír
  • Čermák, Jiří
http://linked.open...ain/vavai/riv/wos
  • 000297394700018
http://linked.open...n/vavai/riv/zamer
issn
  • 0378-7753
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.jpowsour.2011.09.045
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