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  • Kinetics of hydrogen desorption from Mg2NiH4 was studied. Experimental material was prepared by two techniques – by melting and casting and by ball-milling and compacting into pellets. Experimental materials were hydrogen charged at elevated temperature and pressure. The pellets were charged in two different regimes resulting in structures with high fraction of twinned low-temperature phase LT2 and with low fraction of LT2. It was made an attempt to measure diffusion coefficients of hydrogen and its temperature dependence both in high-temperature (HT) and in low-temperature (LT) phases of Mg2NiH4. The measurement was carried out in temperature interval from 449 K to 576 K by the volumetric method. It was found that the LT2 slows-down the desorption rate considerably.
  • Kinetics of hydrogen desorption from Mg2NiH4 was studied. Experimental material was prepared by two techniques – by melting and casting and by ball-milling and compacting into pellets. Experimental materials were hydrogen charged at elevated temperature and pressure. The pellets were charged in two different regimes resulting in structures with high fraction of twinned low-temperature phase LT2 and with low fraction of LT2. It was made an attempt to measure diffusion coefficients of hydrogen and its temperature dependence both in high-temperature (HT) and in low-temperature (LT) phases of Mg2NiH4. The measurement was carried out in temperature interval from 449 K to 576 K by the volumetric method. It was found that the LT2 slows-down the desorption rate considerably. (en)
  • Byla studována kinetika desorpce vodíku z Mg2NiH4. Experimentální materiál byl připraven dvěma způsoby - tavením a odlitím a kluvým mletím a zkompaktováním do tablet. Experimentální materiály byly nasyceny vodíkem za zvýšených teplot. Tablety byly syceny ve dvou režimech za vzniku struktury s vysokým podílem twin nízkoteplotní fáze LT2 a s nízkým podílem LT2. Bylo vyzkoušeno měření difpzních koeficientů vodíku a jejich teplotní závislost ve vysokoteplotní (HT) and nízkoteplotní (LT) fázi Mg2NiH4. Měření proběhla v teplotním intervalu 449 - 576 K volumetrickou metodou. Bylo zjištěno, že LT2 zpomaluje významně rychlost desoprce. (cs)
Title
  • Kinetics of phase transformations in Mg2Ni-H system
  • Kinetics of phase transformations in Mg2Ni-H system (en)
  • Kinetika fázových transformací v systému Mg2Ni-H (cs)
skos:prefLabel
  • Kinetics of phase transformations in Mg2Ni-H system
  • Kinetics of phase transformations in Mg2Ni-H system (en)
  • Kinetika fázových transformací v systému Mg2Ni-H (cs)
skos:notation
  • RIV/68081723:_____/08:00305517!RIV08-AV0-68081723
http://linked.open.../vavai/riv/strany
  • 71;90
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA106/07/0010), Z(AV0Z20410507)
http://linked.open...iv/cisloPeriodika
  • -
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  • 374783
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  • RIV/68081723:_____/08:00305517
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • hydrogen storage; hydrogen diffusion; phase transformations (en)
http://linked.open.../riv/klicoveSlovo
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  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [4F3EE1D208CE]
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  • 138
http://linked.open...iv/tvurceVysledku
  • David, Bohumil
  • Král, Lubomír
  • Čermák, Jiří
  • Stloukal, Ivo
http://linked.open...n/vavai/riv/zamer
issn
  • 1012-0394
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