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Description
  • The paper describes a new standard system of cationic buffers for the measurement of pKas and ionic mobilities of weak bases by capillary zone electrophoresis in presence of a constant concentration chloride present as a counterion. The set of measurements is performed under constant ionic strength and under constant Joule heating. The reliability and advantages of the used system of buffers are verified by the measurement of the above given quantities of pyridine and a group of amines that are known to cause interaction problems.
  • The paper describes a new standard system of cationic buffers for the measurement of pKas and ionic mobilities of weak bases by capillary zone electrophoresis in presence of a constant concentration chloride present as a counterion. The set of measurements is performed under constant ionic strength and under constant Joule heating. The reliability and advantages of the used system of buffers are verified by the measurement of the above given quantities of pyridine and a group of amines that are known to cause interaction problems. (en)
Title
  • Standard systems for measurement of pK values and ionic mobilities 2. Univalent weak bases
  • Standard systems for measurement of pK values and ionic mobilities 2. Univalent weak bases (en)
skos:prefLabel
  • Standard systems for measurement of pK values and ionic mobilities 2. Univalent weak bases
  • Standard systems for measurement of pK values and ionic mobilities 2. Univalent weak bases (en)
skos:notation
  • RIV/68081715:_____/09:00331323!RIV10-AV0-68081715
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/08/1536), P(IAA400310609), P(IAA400310703), Z(AV0Z40310501)
http://linked.open...iv/cisloPeriodika
  • 17
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...dnocenehoVysledku
  • 343377
http://linked.open...ai/riv/idVysledku
  • RIV/68081715:_____/09:00331323
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • CZE; dissociation constant; ionic mobility; univalent weak bases (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [04400171F18B]
http://linked.open...i/riv/nazevZdroje
  • Journal of Chromatography A
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 1216
http://linked.open...iv/tvurceVysledku
  • Boček, Petr
  • Křivánková, Ludmila
  • Gebauer, Petr
  • Šlampová, Andrea
http://linked.open...ain/vavai/riv/wos
  • 000265467200007
http://linked.open...n/vavai/riv/zamer
issn
  • 0021-9673
number of pages
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