About: Solute partitioning between the ionic liquid 1-n-butyl-3-methylimidazolium tetrafluoroborate and supercritical CO2 from capillary-column chromatography

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About: Solute partitioning between the ionic liquid 1-n-butyl-3-methylimidazolium tetrafluoroborate and supercritical CO2 from capillary-column chromatography Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Pomocí kapilární superkritické fluidní chromatografie (SFC) se stacionární iontovou kapalinou (IL) tetrafluoroboritanem 1-n-butyl-3-methylimidazolia a superkritickým oxidem uhličitým jako mobilní fází byly měřeny retenční faktory vybraných solutů v rozsahu 313-353 K a 8.1-23.2 MPa. Za konstantní teploty a hustoty CO2 lze výsledné distribuční konstanty korelovat pomocí lineárních vztahů solvatační energie. Prediktivní schopnost těchto korelací bude užitečná v chemickém inženýrství pro návrh procesů využívajících dvoufázových rozpouštědlových systémů IL-CO2 (cs) Open tubular capillary-column supercritical fluid chromatography (SFC) with room-temperature ionic liquid (RTIL) 1-n-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]) as the stationary liquid and supercritical carbon dioxide (scCO2) as the mobile phase was employed to measure solute retention factors within 313-353 K and 8.1-23.2 MPa. At a particular temperature and density of CO2, solute partition coefficients can be correlated in terms of linear solvation energy relationships. Predictive power of such correlations will important for engineering design of real-world processes employing biphasic RTIL-CO2 solvent systems. Open tubular capillary-column supercritical fluid chromatography (SFC) with room-temperature ionic liquid (RTIL) 1-n-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]) as the stationary liquid and supercritical carbon dioxide (scCO2) as the mobile phase was employed to measure solute retention factors within 313-353 K and 8.1-23.2 MPa. At a particular temperature and density of CO2, solute partition coefficients can be correlated in terms of linear solvation energy relationships. Predictive power of such correlations will important for engineering design of real-world processes employing biphasic RTIL-CO2 solvent systems. (en)
Title	Solute partitioning between the ionic liquid 1-n-butyl-3-methylimidazolium tetrafluoroborate and supercritical CO2 from capillary-column chromatography Solute partitioning between the ionic liquid 1-n-butyl-3-methylimidazolium tetrafluoroborate and supercritical CO2 from capillary-column chromatography (en) Studium distribuce solutů mezi iontovou kapalinu tetrafluoroboritan 1-n-butyl-3-methylimidazolia a superkritický CO2 pomocí chromatografie v kapilárních kolonách (cs)
skos:prefLabel	Solute partitioning between the ionic liquid 1-n-butyl-3-methylimidazolium tetrafluoroborate and supercritical CO2 from capillary-column chromatography Solute partitioning between the ionic liquid 1-n-butyl-3-methylimidazolium tetrafluoroborate and supercritical CO2 from capillary-column chromatography (en) Studium distribuce solutů mezi iontovou kapalinu tetrafluoroboritan 1-n-butyl-3-methylimidazolia a superkritický CO2 pomocí chromatografie v kapilárních kolonách (cs)
skos:notation	RIV/68081715:_____/05:00021362!RIV06-AV0-68081715
http://linked.open.../vavai/riv/strany	15165;15171
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(KJB400310504)
http://linked.open...iv/cisloPeriodika	31
http://linked.open...vai/riv/dodaniDat	2006
http://linked.open...aciTvurceVysledku	Roth, Michal Planeta, Josef
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav analytické chemie AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	543442
http://linked.open...ai/riv/idVysledku	RIV/68081715:_____/05:00021362
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	ionic liquid - supercritical CO2 system; solute partition coefficient; linear solvation energy relationship (en)
http://linked.open.../riv/klicoveSlovo	solute partition coefficient ionic liquid linear solvation energy relationship
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[027C9F248B28]
http://linked.open...i/riv/nazevZdroje	Journal of Physical Chemistry B
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...vavai/riv/projekt	Development and Applications of the Column Technology in SFC and HPLC
http://linked.open...UplatneniVysledku	2005
http://linked.open...v/svazekPeriodika	109
http://linked.open...iv/tvurceVysledku	Roth, Michal Planeta, Josef
issn	1520-6106
number of pages	7 (xsd:int)

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