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  • The analysis records in capillary electrophoresis may involve regions with extremely strong electromigration dispersion of peaks. This is due to the existence of more centers of symmetry in a given electrolyte system. This paper shows that even such simple and frequently used electrolyte systems as phosphate buffer may exhibit more than one center of symmetry. By using the peak shape diagram approach we have revealed that neutral and alkaline phosphate buffers have two centers of symmetry and one center of extreme dispersion. Model experiments confirmed this new important discovery.
  • The analysis records in capillary electrophoresis may involve regions with extremely strong electromigration dispersion of peaks. This is due to the existence of more centers of symmetry in a given electrolyte system. This paper shows that even such simple and frequently used electrolyte systems as phosphate buffer may exhibit more than one center of symmetry. By using the peak shape diagram approach we have revealed that neutral and alkaline phosphate buffers have two centers of symmetry and one center of extreme dispersion. Model experiments confirmed this new important discovery. (en)
Title
  • Capillary zone electrophoresis in phosphate buffer - known or unknown?
  • Capillary zone electrophoresis in phosphate buffer - known or unknown? (en)
skos:prefLabel
  • Capillary zone electrophoresis in phosphate buffer - known or unknown?
  • Capillary zone electrophoresis in phosphate buffer - known or unknown? (en)
skos:notation
  • RIV/68081715:_____/00:25200054!RIV/2003/AV0/A25003/N
http://linked.open.../vavai/riv/strany
  • 89;93
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/99/0044), P(IAA4031703), P(VS96021), P(VS97014), Z(AV0Z4031919)
http://linked.open...iv/cisloPeriodika
  • 1+2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...dnocenehoVysledku
  • 706095
http://linked.open...ai/riv/idVysledku
  • RIV/68081715:_____/00:25200054
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • N/A (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [509D567006AC]
http://linked.open...i/riv/nazevZdroje
  • Journal of Chromatography A
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...ocetUcastnikuAkce
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 894
http://linked.open...iv/tvurceVysledku
  • Boček, Petr
  • Gebauer, Petr
  • Pantůčková, Pavla
http://linked.open...n/vavai/riv/zamer
issn
  • 0021-9673
number of pages
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