About: Sample self-stacking in capillary zone electrophoresis: Behavior of samples containing multiple major coionic components.     Goto   Sponge   NotDistinct   Permalink

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Description
  • A major co-ionic sample component can considerably increase the detection limits of minor analytes by concentrating them transiently. Sometimes such stacking is deteriorated by the presence of another macrocomponent of like charge in the sample. A theoretical approach was elaborated which describes the separation process and finds the conditions that define whether transient isotachophoretic stacking of the analyte takes place or not. Theoretical considerations are illustrated by computer simulations and verified experimentally. Examples are demonstrated for model serum samples.
  • A major co-ionic sample component can considerably increase the detection limits of minor analytes by concentrating them transiently. Sometimes such stacking is deteriorated by the presence of another macrocomponent of like charge in the sample. A theoretical approach was elaborated which describes the separation process and finds the conditions that define whether transient isotachophoretic stacking of the analyte takes place or not. Theoretical considerations are illustrated by computer simulations and verified experimentally. Examples are demonstrated for model serum samples. (en)
Title
  • Sample self-stacking in capillary zone electrophoresis: Behavior of samples containing multiple major coionic components.
  • Sample self-stacking in capillary zone electrophoresis: Behavior of samples containing multiple major coionic components. (en)
skos:prefLabel
  • Sample self-stacking in capillary zone electrophoresis: Behavior of samples containing multiple major coionic components.
  • Sample self-stacking in capillary zone electrophoresis: Behavior of samples containing multiple major coionic components. (en)
skos:notation
  • RIV/68081715:_____/00:25200034!RIV/2003/AV0/A25003/N
http://linked.open.../vavai/riv/strany
  • 2797;2808
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/99/0044), P(IAA4031703), P(VS96021), Z(AV0Z4031919)
http://linked.open...iv/cisloPeriodika
  • 14
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
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http://linked.open...dnocenehoVysledku
  • 725891
http://linked.open...ai/riv/idVysledku
  • RIV/68081715:_____/00:25200034
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  • N/A (en)
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http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [56419D2018EC]
http://linked.open...i/riv/nazevZdroje
  • Electrophoresis
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 21
http://linked.open...iv/tvurceVysledku
  • Boček, Petr
  • Křivánková, Ludmila
  • Gebauer, Petr
  • Pantůčková, Pavla
  • Thormann, W.
http://linked.open...n/vavai/riv/zamer
issn
  • 0173-0835
number of pages
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