About: Solution phase thermodynamics of strong electrolytes based on ionic concentrations, hydration numbers and volumes of dissolved entities

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Solution phase thermodynamics of strong electrolytes based on ionic concentrations, hydration numbers and volumes of dissolved entities Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	This article summarizes the successful restoration of Arrhenius' theory of electrolytic dissociation founded 130 years ago. His idea of using the conductivity ratio for the degree of dissociation was a breakthrough in interpreting the properties of dilute solutions. For higher concentrations, as it was not satisfactory, attempts were being made to improve the methods of obtaining the degrees of dissociation. However, the latter was prematurely replaced by the empirical activity coefficient correction factors. Subsequently, the success of the Debye-Huckel (D-H) theory of inter-ionic interaction between free ions in explaining the properties of dilute solutions was taken to mean complete dissociation at all concentrations and interpretation of solution properties amounted to extending the D-H equations by the gradual addition of more parameters. At the end of six decades the equations became so complex that they failed to provide a unified interpretation of the causes of non-ideality at all concentrations and a molecular insight into the observed phenomena. This article summarizes the successful restoration of Arrhenius' theory of electrolytic dissociation founded 130 years ago. His idea of using the conductivity ratio for the degree of dissociation was a breakthrough in interpreting the properties of dilute solutions. For higher concentrations, as it was not satisfactory, attempts were being made to improve the methods of obtaining the degrees of dissociation. However, the latter was prematurely replaced by the empirical activity coefficient correction factors. Subsequently, the success of the Debye-Huckel (D-H) theory of inter-ionic interaction between free ions in explaining the properties of dilute solutions was taken to mean complete dissociation at all concentrations and interpretation of solution properties amounted to extending the D-H equations by the gradual addition of more parameters. At the end of six decades the equations became so complex that they failed to provide a unified interpretation of the causes of non-ideality at all concentrations and a molecular insight into the observed phenomena. (en)
Title	Solution phase thermodynamics of strong electrolytes based on ionic concentrations, hydration numbers and volumes of dissolved entities Solution phase thermodynamics of strong electrolytes based on ionic concentrations, hydration numbers and volumes of dissolved entities (en)
skos:prefLabel	Solution phase thermodynamics of strong electrolytes based on ionic concentrations, hydration numbers and volumes of dissolved entities Solution phase thermodynamics of strong electrolytes based on ionic concentrations, hydration numbers and volumes of dissolved entities (en)
skos:notation	RIV/68081707:_____/13:00440146!RIV15-AV0-68081707
http://linked.open...avai/riv/aktivita	I
http://linked.open...avai/riv/aktivity	I
http://linked.open...iv/cisloPeriodika	6
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Heyrovská, Rajalakshmi
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Biofyzikální ústav AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	106272
http://linked.open...ai/riv/idVysledku	RIV/68081707:_____/13:00440146
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Solution thermodynamics; Aqueous electrolytes; Partial electrolytic dissociation (en)
http://linked.open.../riv/klicoveSlovo	Aqueous electrolytes Partial electrolytic dissociation Solution thermodynamics
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[5CD2D6F1E8AD]
http://linked.open...i/riv/nazevZdroje	Structural Chemistry
http://linked.open...in/vavai/riv/obor	BO
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	1 (xsd:int)
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	24
http://linked.open...iv/tvurceVysledku	Heyrovská, Raji
http://linked.open...ain/vavai/riv/wos	000328326800012
issn	1040-0400
number of pages	7 (xsd:int)
http://bibframe.org/vocab/doi	10.1007/s11224-013-0256-7

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 112 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software