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  • Chronopotentiometric stripping (CPS) peak H in proteins is due to the catalytic hydrogen evolution reaction (CHER) involving amino acid residues. This peak is sensitive to changes in protein structures, representing a new tool in protein research. Here we show on the ground of studies of CPS behavior of four angiotensin peptides that at neutral pH arginine plays a critical role in CHER at Hg electrode, while participation of histidine residues in this reaction is very weak. At carbon electrode tyrosine residues produce an oxidation peak close to 0.7 V but the presence of histidine in angiotensins is not manifested by any oxidation peak. (C) 2013 Elsevier B.V. All rights reserved.
  • Chronopotentiometric stripping (CPS) peak H in proteins is due to the catalytic hydrogen evolution reaction (CHER) involving amino acid residues. This peak is sensitive to changes in protein structures, representing a new tool in protein research. Here we show on the ground of studies of CPS behavior of four angiotensin peptides that at neutral pH arginine plays a critical role in CHER at Hg electrode, while participation of histidine residues in this reaction is very weak. At carbon electrode tyrosine residues produce an oxidation peak close to 0.7 V but the presence of histidine in angiotensins is not manifested by any oxidation peak. (C) 2013 Elsevier B.V. All rights reserved. (en)
Title
  • Electrochemical reduction and oxidation signals of angiotensin peptides. Role of individual amino acid residues
  • Electrochemical reduction and oxidation signals of angiotensin peptides. Role of individual amino acid residues (en)
skos:prefLabel
  • Electrochemical reduction and oxidation signals of angiotensin peptides. Role of individual amino acid residues
  • Electrochemical reduction and oxidation signals of angiotensin peptides. Role of individual amino acid residues (en)
skos:notation
  • RIV/68081707:_____/13:00394828!RIV14-GA0-68081707
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GAP301/11/2055)
http://linked.open...iv/cisloPeriodika
  • JUN 2013
http://linked.open...vai/riv/dodaniDat
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  • 72362
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  • RIV/68081707:_____/13:00394828
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  • CARBON ELECTRODES; HYDROGEN EVOLUTION; BIOACTIVE PEPTIDES (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [740DBE5041D9]
http://linked.open...i/riv/nazevZdroje
  • Electrochemistry Communications
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  • 31
http://linked.open...iv/tvurceVysledku
  • Ostatná, Veronika
  • Paleček, Emil
  • Dorčák, Vlastimil
http://linked.open...ain/vavai/riv/wos
  • 000319236800022
issn
  • 1388-2481
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.elecom.2013.03.016
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