About: Voltammetry of Os(VI)-modified polysaccharides at carbon electrodes

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	We show that polysaccarides (PSs, such as dextran and mannan) can be chemically modified by Os(VI) complexes, yielding electroactive adducts. Os(VI) complexes with different ligands (e.g., temed and 2,2'-bipyridine) produced at pyrolytic graphite electrodes redox couples at different potentials suitable for %22multicolor%22 labeling of PSs and for studies of ligand exchange kinetics. PS-Os(VI)L adducts can be determined not only in their purified forms but also in the reaction mixtures. We show that polysaccarides (PSs, such as dextran and mannan) can be chemically modified by Os(VI) complexes, yielding electroactive adducts. Os(VI) complexes with different ligands (e.g., temed and 2,2'-bipyridine) produced at pyrolytic graphite electrodes redox couples at different potentials suitable for %22multicolor%22 labeling of PSs and for studies of ligand exchange kinetics. PS-Os(VI)L adducts can be determined not only in their purified forms but also in the reaction mixtures. (en)
Title	Voltammetry of Os(VI)-modified polysaccharides at carbon electrodes Voltammetry of Os(VI)-modified polysaccharides at carbon electrodes (en)
skos:prefLabel	Voltammetry of Os(VI)-modified polysaccharides at carbon electrodes Voltammetry of Os(VI)-modified polysaccharides at carbon electrodes (en)
skos:notation	RIV/68081707:_____/09:00328610!RIV10-MSM-68081707
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA301/07/0490), P(LC06035), Z(AV0Z50040507), Z(AV0Z50040702), Z(MSM0021622415)
http://linked.open...iv/cisloPeriodika	15
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Paleček, Emil Trefulka, Mojmír
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Biofyzikální ústav AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	349872
http://linked.open...ai/riv/idVysledku	RIV/68081707:_____/09:00328610
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	chemical modification of polysaccharides; Os(VI)L-polysaccharide adducts; pyrolytic graphite electrodes (en)
http://linked.open.../riv/klicoveSlovo	chemical modification of polysaccharides Os(VI)L-polysaccharide adducts pyrolytic graphite electrodes
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[7581F2F65ACA]
http://linked.open...i/riv/nazevZdroje	Electroanalysis
http://linked.open...in/vavai/riv/obor	BO
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...vavai/riv/projekt	Centre of Biophysical Chemistry, Bioelectrochemistry and Bioanalysis. New Tools for Genomics, Proteomics and Biomedicine. Protein and DNA-modified electrodes. New tools for biomedicine
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	21
http://linked.open...iv/tvurceVysledku	Paleček, Emil Trefulka, Mojmír
http://linked.open...ain/vavai/riv/wos	000268790300015
http://linked.open...n/vavai/riv/zamer	Biophysics of dynamic structures and functions of biological systems Genome and epigenome: 1D and 3D Structure, Dynamics, Interactions with Proteins and Functions Molecular basis of cell and tissue regulations
issn	1040-0397
number of pages	4 (xsd:int)

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