About: Microreactor as Efficient Tool for Light Induced Oxidation Reactions

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	A photo microreactor (PMR) of unique parameters was operated in the degradation of 4-chlorophenol with sulfonated zinc phthalocyanine (ZnPcSmix). This sensitizer was chosen as model homogeneous photocatalyst to evaluate operation parameters and efficiency of the PMR. All reactions were carried out in deuterium oxide to maximize the life-time of the generated singlet oxygen species. In parallel same model oxidations were performed in a laboratory batch system using identical optical arrangements. Both systems were optimized and evaluated with help of kinetic models and rationally compared. It was shown the PMR arrangement revealed much higher process efficacy. Construction details and optimized operating parameters of the PMR are provided and discussed in details. A photo microreactor (PMR) of unique parameters was operated in the degradation of 4-chlorophenol with sulfonated zinc phthalocyanine (ZnPcSmix). This sensitizer was chosen as model homogeneous photocatalyst to evaluate operation parameters and efficiency of the PMR. All reactions were carried out in deuterium oxide to maximize the life-time of the generated singlet oxygen species. In parallel same model oxidations were performed in a laboratory batch system using identical optical arrangements. Both systems were optimized and evaluated with help of kinetic models and rationally compared. It was shown the PMR arrangement revealed much higher process efficacy. Construction details and optimized operating parameters of the PMR are provided and discussed in details. (en)
Title	Microreactor as Efficient Tool for Light Induced Oxidation Reactions Microreactor as Efficient Tool for Light Induced Oxidation Reactions (en)
skos:prefLabel	Microreactor as Efficient Tool for Light Induced Oxidation Reactions Microreactor as Efficient Tool for Light Induced Oxidation Reactions (en)
skos:notation	RIV/67985858:_____/14:00436061!RIV15-AV0-67985858
http://linked.open...avai/riv/aktivita	I
http://linked.open...avai/riv/aktivity	I
http://linked.open...iv/cisloPeriodika	NOV 1
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Klusoň, Petr Křišťál, Jiří Krystyník, Pavel Drhová, Magdalena
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav chemických procesů AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	29202
http://linked.open...ai/riv/idVysledku	RIV/67985858:_____/14:00436061
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	photo microreactor; phthalocyanine; chlorophenol oxidation (en)
http://linked.open.../riv/klicoveSlovo	phthalocyanine chlorophenol oxidation photo microreactor
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[B36211F57E63]
http://linked.open...i/riv/nazevZdroje	Chemical Engineering Journal
http://linked.open...in/vavai/riv/obor	CI
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	255
http://linked.open...iv/tvurceVysledku	Klusoň, Petr Křišťál, Jiří Krystyník, Pavel Drhová, Magdalena Hejda, S. Buzek, D.
http://linked.open...ain/vavai/riv/wos	000341470800023
issn	1385-8947
number of pages	7 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.cej.2014.06.052

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