About: Carbosilane Metallodendrimers with Titanocene Dichloride end Groups

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Carbosilane metallodendrimers containing substituted titanocene dichloride end groups were prepared using hydrosilylation as the capping reaction. Two complementary pathways were followed: hydrosilylation of ω-alkenyl-substituted titanocene dichloride complexes with SiH bond terminated dendrimers and hydrosilylation of vinyl terminated dendritic materials with 3-(dimethylsilyl)propyl-substituted titanocene dichloride. The former procedure provided dendrimers of the first generation with four end units and of the second generation with eight end units. The latter method gave dendrititic wedges and dendrimers up to the second generation with 16 peripheral titanocene dichloride units and molecular weight 7070 Da. Dendritic materials were purified by GPC and characterized by MALDI-TOF mass spectrometry and ESI-TOF mass spectrometry (metallodendrimers) and also by multinuclear NMR. Carbosilane metallodendrimers containing substituted titanocene dichloride end groups were prepared using hydrosilylation as the capping reaction. Two complementary pathways were followed: hydrosilylation of ω-alkenyl-substituted titanocene dichloride complexes with SiH bond terminated dendrimers and hydrosilylation of vinyl terminated dendritic materials with 3-(dimethylsilyl)propyl-substituted titanocene dichloride. The former procedure provided dendrimers of the first generation with four end units and of the second generation with eight end units. The latter method gave dendrititic wedges and dendrimers up to the second generation with 16 peripheral titanocene dichloride units and molecular weight 7070 Da. Dendritic materials were purified by GPC and characterized by MALDI-TOF mass spectrometry and ESI-TOF mass spectrometry (metallodendrimers) and also by multinuclear NMR. (en)
Title	Carbosilane Metallodendrimers with Titanocene Dichloride end Groups Carbosilane Metallodendrimers with Titanocene Dichloride end Groups (en)
skos:prefLabel	Carbosilane Metallodendrimers with Titanocene Dichloride end Groups Carbosilane Metallodendrimers with Titanocene Dichloride end Groups (en)
skos:notation	RIV/67985858:_____/12:00383459!RIV13-AV0-67985858
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(LC06070)
http://linked.open...iv/cisloPeriodika	19
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Čermák, Jan Sýkora, Jan Strašák, Tomáš
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav chemických procesů AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	125985
http://linked.open...ai/riv/idVysledku	RIV/67985858:_____/12:00383459
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	dendrimers; titanocene; hydrosilylation (en)
http://linked.open.../riv/klicoveSlovo	dendrimers titanocene hydrosilylation
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[E2CA771C8308]
http://linked.open...i/riv/nazevZdroje	Organometallics
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...vavai/riv/projekt	The structure and synthetic applications of transition metal complexes
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	31
http://linked.open...iv/tvurceVysledku	Horský, Jiří Sýkora, Jan Čermák, Jan Walterová, Zuzana Harakat, D. Jaroschik, F. Strašák, Tomáš
http://linked.open...ain/vavai/riv/wos	000309488500009
issn	0276-7333
number of pages	8 (xsd:int)
http://bibframe.org/vocab/doi	10.1021/om300559y

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