About: Total Oxidation of Model Volatile Organic Compounds over Some Commercial Catalysts

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Commercial VOC oxidation catalysts can be used as comparative materials during development of new or improved catalysts. The objective of this study was to investigate physicochemical properties of EnviCat commercial catalysts and their performance in total oxidation of three model compounds (dichloromethane, toluene and ethanol) at laboratory scale. The reactivity of model VOC was decreasing in the order ethanol > toluene > dichloromethane. The Cu-Mn/Al catalyst was found to be the most active and selective catalyst in ethanol oxidation. In oxidation of dichloromethane, the Pt-Pd/Al-Ce catalyst with 0.10 wt. % Pt+Pd was the most active, while the most selective one (giving the highest HCl yield) was the Pt-Pd/Al catalyst containing 0.24 wt. % Pt+Pd. In toluene oxidation, the Pt-Pd/Al catalyst with 0.24 wt. % Pt+Pd possessed the highest activity; the selectivity to CO2 was 100 % for all investigated catalyst. Commercial VOC oxidation catalysts can be used as comparative materials during development of new or improved catalysts. The objective of this study was to investigate physicochemical properties of EnviCat commercial catalysts and their performance in total oxidation of three model compounds (dichloromethane, toluene and ethanol) at laboratory scale. The reactivity of model VOC was decreasing in the order ethanol > toluene > dichloromethane. The Cu-Mn/Al catalyst was found to be the most active and selective catalyst in ethanol oxidation. In oxidation of dichloromethane, the Pt-Pd/Al-Ce catalyst with 0.10 wt. % Pt+Pd was the most active, while the most selective one (giving the highest HCl yield) was the Pt-Pd/Al catalyst containing 0.24 wt. % Pt+Pd. In toluene oxidation, the Pt-Pd/Al catalyst with 0.24 wt. % Pt+Pd possessed the highest activity; the selectivity to CO2 was 100 % for all investigated catalyst. (en)
Title	Total Oxidation of Model Volatile Organic Compounds over Some Commercial Catalysts Total Oxidation of Model Volatile Organic Compounds over Some Commercial Catalysts (en)
skos:prefLabel	Total Oxidation of Model Volatile Organic Compounds over Some Commercial Catalysts Total Oxidation of Model Volatile Organic Compounds over Some Commercial Catalysts (en)
skos:notation	RIV/67985858:_____/12:00380234!RIV13-AV0-67985858
http://linked.open...avai/riv/aktivita	I P
http://linked.open...avai/riv/aktivity	I, P(FR-TI1/059)
http://linked.open...iv/cisloPeriodika	NOV 7
http://linked.open...vai/riv/dodaniDat	2013
http://linked.open...aciTvurceVysledku	Matějová, Lenka Šolcová, Olga Topka, Pavel Jirátová, Květa
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav chemických procesů AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	174649
http://linked.open...ai/riv/idVysledku	RIV/67985858:_____/12:00380234
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	volatile organic compounds; oxidation; ethanol (en)
http://linked.open.../riv/klicoveSlovo	volatile organic compounds oxidation ethanol
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[6449E8DEF6DA]
http://linked.open...i/riv/nazevZdroje	Applied Catalysis A - General
http://linked.open...in/vavai/riv/obor	DM
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	*Utilization of combined thermal desorption and catalytic oxidation methods for solid waste decontamination
http://linked.open...UplatneniVysledku	2012
http://linked.open...v/svazekPeriodika	443
http://linked.open...iv/tvurceVysledku	Matějová, Lenka Topka, Pavel Šolcová, Olga Jirátová, Květa
http://linked.open...ain/vavai/riv/wos	000309644400005
issn	0926-860X
number of pages	10 (xsd:int)
http://bibframe.org/vocab/doi	10.1016/j.apcata.2012.07.018

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