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  • The effect of repulsive interactions (geometrical packing of molecules) on mixing properties is examined considering hard sphere solutes of different diameters in the hard sphere and pseudo-hard body solvents. It is shown that the fluid of pseudo-hard bodies, representing repulsive interactions in water, captures, without any parameter adjustment, the experimentally observed decrease of the partial molar volume of nonpolar solutes (hard spheres) at their low concentrations when compared to that in a nonpolar (hard sphere) solvent.
  • The effect of repulsive interactions (geometrical packing of molecules) on mixing properties is examined considering hard sphere solutes of different diameters in the hard sphere and pseudo-hard body solvents. It is shown that the fluid of pseudo-hard bodies, representing repulsive interactions in water, captures, without any parameter adjustment, the experimentally observed decrease of the partial molar volume of nonpolar solutes (hard spheres) at their low concentrations when compared to that in a nonpolar (hard sphere) solvent. (en)
Title
  • Excess Properties of Aqueous Solutions: Hard Spheres versus Pseudo-Hard Bodies
  • Excess Properties of Aqueous Solutions: Hard Spheres versus Pseudo-Hard Bodies (en)
skos:prefLabel
  • Excess Properties of Aqueous Solutions: Hard Spheres versus Pseudo-Hard Bodies
  • Excess Properties of Aqueous Solutions: Hard Spheres versus Pseudo-Hard Bodies (en)
skos:notation
  • RIV/67985858:_____/11:00368376!RIV12-AV0-67985858
http://linked.open...avai/riv/aktivita
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  • I, P(IAA400720802), Z(AV0Z40720504)
http://linked.open...iv/cisloPeriodika
  • 4
http://linked.open...vai/riv/dodaniDat
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  • 198602
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  • RIV/67985858:_____/11:00368376
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  • partial molar volume; primitive models; thermodynamic properties (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [F30F6CB5EA25]
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  • Molecular Physics
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  • 109
http://linked.open...iv/tvurceVysledku
  • Nezbeda, Ivo
  • Rouha, M.
http://linked.open...ain/vavai/riv/wos
  • 000287400900013
http://linked.open...n/vavai/riv/zamer
issn
  • 0026-8976
number of pages
http://bibframe.org/vocab/doi
  • 10.1080/00268976.2010.542779
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