About: Quarternary Ammonium Salts as Reaction Media for Asymmetric Hydrogenation of beta-Ketoesters     Goto   Sponge   NotDistinct   Permalink

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Description
  • Asymetrická hydrogenace methyl acetoacetátu v iontových kapalinách, obecného názvu n-alky-triethylammonium bis(trifluormethylsulfonyl)imid, běží s vysokou selektivitou, produkty lze jednoduše oddělit extrakcí do organického rozpouštědla a katalyzátor recyklovat. Použití těchto iontových kapalin k imobilizaci katalyzátoru s sebou nese i určité nevýhody. Ty jsou diskutovány v tomto příspěvku. (cs)
  • The result in this contribution presented that the use of n-alkyl-triethylammonium bis(trifluoromethane sulfonyl) imides as the immobilization media is promissing, in spite of their negative effect on the kinetic parameters, aspecially turnover rate and enantioselectivity. In this case, asymmetric hydrogenation of methyl acetoacetate can proceed with high selectivity, products can be separated anf the catalyst re-used.
  • The result in this contribution presented that the use of n-alkyl-triethylammonium bis(trifluoromethane sulfonyl) imides as the immobilization media is promissing, in spite of their negative effect on the kinetic parameters, aspecially turnover rate and enantioselectivity. In this case, asymmetric hydrogenation of methyl acetoacetate can proceed with high selectivity, products can be separated anf the catalyst re-used. (en)
Title
  • Quarternary Ammonium Salts as Reaction Media for Asymmetric Hydrogenation of beta-Ketoesters
  • Quarternary Ammonium Salts as Reaction Media for Asymmetric Hydrogenation of beta-Ketoesters (en)
  • Asymetrická hydrogenace beta-ketoesteru v iontových kapalinách (cs)
skos:prefLabel
  • Quarternary Ammonium Salts as Reaction Media for Asymmetric Hydrogenation of beta-Ketoesters
  • Quarternary Ammonium Salts as Reaction Media for Asymmetric Hydrogenation of beta-Ketoesters (en)
  • Asymetrická hydrogenace beta-ketoesteru v iontových kapalinách (cs)
skos:notation
  • RIV/67985858:_____/08:00313284!RIV09-AV0-67985858
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GD203/08/H032), P(KAN400720701), Z(AV0Z40720504)
http://linked.open...vai/riv/dodaniDat
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  • 391279
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  • RIV/67985858:_____/08:00313284
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  • hydrogenation reactions; catalysts (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [BD3776CF7AC9]
http://linked.open...v/mistoKonaniAkce
  • Štrbské Pleso
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  • Bratislava
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  • Book of Abstracts
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  • Klusoň, Petr
  • Floriš, T.
  • Storch, Jan
  • Bartek, L.
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
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  • Slovenská technická univerzita v Bratislave
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  • 978-80-227-2923-9
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