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| rdf:type
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| Description
| - A series of novel diphosphinoazine rhodium amido carbonyl complexes [{R2PCH=C(But)-NN=C(But)CH2PR2}Rh(CO)] (R = Ph, Pri, c-C6H11, But) was prepared. The crystal structures of three complexes were determined by X-ray diffraction showing the complexes to be essentially planar with mutual trans arrangement of phosphine groups and nitrogens trans to carbonyl ligands. Measurement of valence vibration frequencies of carbonyl groups in the complexes allowed to estimate the electron density on the rhodium centre. In the neutral series of complexes electron dona. The tert-butyl cationic complex undergoes in a low yield an unusual diphosphinoazine bond cleavage with simultaneous oxidation of the metal resulting in a binuclear bis(iminophosphine)dirhodium complex.
- A series of novel diphosphinoazine rhodium amido carbonyl complexes [{R2PCH=C(But)-NN=C(But)CH2PR2}Rh(CO)] (R = Ph, Pri, c-C6H11, But) was prepared. The crystal structures of three complexes were determined by X-ray diffraction showing the complexes to be essentially planar with mutual trans arrangement of phosphine groups and nitrogens trans to carbonyl ligands. Measurement of valence vibration frequencies of carbonyl groups in the complexes allowed to estimate the electron density on the rhodium centre. In the neutral series of complexes electron dona. The tert-butyl cationic complex undergoes in a low yield an unusual diphosphinoazine bond cleavage with simultaneous oxidation of the metal resulting in a binuclear bis(iminophosphine)dirhodium complex. (en)
- Byla připravena série nových difosfinoazinových amido-karbonylových komplexů rhodia. Rentgenovou difrakcí byly určeny krystalové struktury tří komplexů ukazující v podstatě planární konfiguraci s vzájemným trans uspořádáním fosfinových skupin a trans uspořádáním dusíku a karbonylových ligandů. Měření frekvencí valenční vibrace karbonylových skupin v komplexech umožnilo odhadnout elektronovou hustotu na rhodném centru. Terc-butylový kationtový complex podléhá v nízkém výtěžku neobvyklému štěpení difosfinoazinové vazby se současnou oxidací kovu a vzniku bunukleárního bis(iminofosfin)rhodného komplexu. (cs)
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| Title
| - Square-planar Diphosphinoazine Rhodium(I) Amido Carbonyl Complexes with an Unsymmetrical PNP’ Pincer-type Coordination
- Čtvercově planární difosfinoazinové amido-karbonylové komplexy rhodia(I) s nesymetrickou PNP' koordinací klešťového typu. (cs)
- Square-planar Diphosphinoazine Rhodium(I) Amido Carbonyl Complexes with an Unsymmetrical PNP’ Pincer-type Coordination (en)
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| skos:prefLabel
| - Square-planar Diphosphinoazine Rhodium(I) Amido Carbonyl Complexes with an Unsymmetrical PNP’ Pincer-type Coordination
- Čtvercově planární difosfinoazinové amido-karbonylové komplexy rhodia(I) s nesymetrickou PNP' koordinací klešťového typu. (cs)
- Square-planar Diphosphinoazine Rhodium(I) Amido Carbonyl Complexes with an Unsymmetrical PNP’ Pincer-type Coordination (en)
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| skos:notation
| - RIV/67985858:_____/08:00312451!RIV09-AV0-67985858
|
| http://linked.open...avai/riv/aktivita
| |
| http://linked.open...avai/riv/aktivity
| - P(GA203/01/0554), P(GA203/06/0738), P(LC06070), Z(AV0Z40720504), Z(MSM0021620857)
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
| |
| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
| |
| http://linked.open...ai/riv/idVysledku
| - RIV/67985858:_____/08:00312451
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| http://linked.open...riv/jazykVysledku
| |
| http://linked.open.../riv/klicovaSlova
| - diphosphinoazines; rhodium carbonyl complexes; pincer complexes (en)
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| http://linked.open.../riv/klicoveSlovo
| |
| http://linked.open...odStatuVydavatele
| - CH - Švýcarská konfederace
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| http://linked.open...ontrolniKodProRIV
| |
| http://linked.open...i/riv/nazevZdroje
| - Journal of Organometallic Chemistry
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| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...vavai/riv/projekt
| |
| http://linked.open...UplatneniVysledku
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| http://linked.open...v/svazekPeriodika
| |
| http://linked.open...iv/tvurceVysledku
| - Císařová, I.
- Sýkora, Jan
- Čermák, Jan
- Pošta, Martin
- Vojtíšek, P.
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| http://linked.open...ain/vavai/riv/wos
| |
| http://linked.open...n/vavai/riv/zamer
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| issn
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| number of pages
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