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  • Evaluation of micropore volume and mesopore surface area in microporous-mesoporous samples is presented. A series of mechanical mixtures of microporous zeolite NaY, and mesoporous gama-alumina was used for verification of the applicability of the (three-parameter) modified BET equation. The nitrogen adsorption isotherms (77 K) were analyzed by the modified (three parameters) BET equation and compared with the independent textural information obtained a) from t-plots (with the standard isotherm of nonporous alfa-alumina and the standard isotherms of Lecloux-Pirard) and b) by subtracting the isotherm of the parent NaY from mixed sample isotherms. Similarly, nitrogen adsorption isotherms of rutile samples with micropores blocked by n-nonane, from the literature were tested. For illustration, the failure of classic (two-parameter) BET equation for microporous-mesoporous samples is demonstrated.
  • Evaluation of micropore volume and mesopore surface area in microporous-mesoporous samples is presented. A series of mechanical mixtures of microporous zeolite NaY, and mesoporous gama-alumina was used for verification of the applicability of the (three-parameter) modified BET equation. The nitrogen adsorption isotherms (77 K) were analyzed by the modified (three parameters) BET equation and compared with the independent textural information obtained a) from t-plots (with the standard isotherm of nonporous alfa-alumina and the standard isotherms of Lecloux-Pirard) and b) by subtracting the isotherm of the parent NaY from mixed sample isotherms. Similarly, nitrogen adsorption isotherms of rutile samples with micropores blocked by n-nonane, from the literature were tested. For illustration, the failure of classic (two-parameter) BET equation for microporous-mesoporous samples is demonstrated. (en)
  • Za účelem ověření a důkazu správného vyhodnocení texturních vlastností (objemu pórů a specifického povrchu) mikro-mesoporézních materiálů byla připravena série směsných vzorků obsahujících mikroporézní zeolit NaY a mesoporézní gama-aluminu. Adsorpční izotermy dusíku (při 77K) byly analyzovány pomocí tříparametrové BET rovnice a získané výsledky (texturní vlastnosti) byly porovnány s nezávislými výsledky z t-plotů (za využití standardní izotermy alfa-aluminy a Lecloux-Pirarda) a odečtením izotermy zeolitu NaY od izoterem směsných vzorků. Porovnáním výsledků bylo rovněž demonstrováno chybné využití klasické BET rovnice k vyhodnocení texturních vlastností mikro-mesoporézních materiálů. (cs)
Title
  • The Modified Bet Equation for Correct Determination of Texture Properties in
  • The Modified Bet Equation for Correct Determination of Texture Properties in (en)
  • Modifikovaná BET rovnice k správné interpretaci texturních vlastností mikroporézních-mesoporézních materiálů (cs)
skos:prefLabel
  • The Modified Bet Equation for Correct Determination of Texture Properties in
  • The Modified Bet Equation for Correct Determination of Texture Properties in (en)
  • Modifikovaná BET rovnice k správné interpretaci texturních vlastností mikroporézních-mesoporézních materiálů (cs)
skos:notation
  • RIV/67985858:_____/08:00309208!RIV09-AV0-67985858
http://linked.open...avai/riv/aktivita
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  • P(IAA4072404), P(KAN400720701), Z(AV0Z40720504)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 380217
http://linked.open...ai/riv/idVysledku
  • RIV/67985858:_____/08:00309208
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http://linked.open.../riv/klicovaSlova
  • adsorption isotherm; modified BET equation; t-plots (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [932850C0C7CB]
http://linked.open...v/mistoKonaniAkce
  • Tatranské Matliare
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  • Bratislava
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  • Proceedings
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http://linked.open...iv/tvurceVysledku
  • Matějová, Lenka
  • Šolcová, Olga
  • Součková, Helena
  • Šnajdaufová, Hana
  • Hudec, P.
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
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  • Slovak Society of Chemical Engineering
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  • 978-80-227-2903-1
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