About: Tetramethyl(perfluoroalkyl)cyclopentadienyl Rhodium(III) Complexes Containing Phosphorus and Nitrogen Monodentate Donors. Crystal Structure of [(h5-C5Me4C4F9)Rh(PPri3)Cl2]

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About: Tetramethyl(perfluoroalkyl)cyclopentadienyl Rhodium(III) Complexes Containing Phosphorus and Nitrogen Monodentate Donors. Crystal Structure of [(h5-C5Me4C4F9)Rh(PPri3)Cl2] Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Štěpení dvojitého ?-halo můstku v komplexech [(C5Me4CnF2n+1)RhX2]2 (n = 4, 6; X = Cl, Br) dvouelektronovými monodentátními P-donory jako jsou fosfiny nebo fosfity nebo monodentátními N-donory jako jsou heterocyklické aminy odvozené od pyridinu poskytlo mononukleární Rh(III) komplexy [(C5Me4CnF2n+1)RhX2L] (L = dvouelektronový donor) typu pianová židlička. Krystalová struktura [(?5-C5Me4C4F9)Rh(PPri3)Cl2] byla stanovena rentgenovou difrakcí. Sloučenina vykazuje pseudotetraedrické uspořádání ligandů kolem centrálního atomu. Perfluoralkylový řetězec je v poloze odvrácené od fosfinového ligandu, ne však úplně, po projekci do roviny kruhu je úhel P – centroid kruhu – CF2 roven 166°. (cs) Cleavage of a double m-halo bridge in complexes [(C5Me4CnF2n+1)RhX2]2 (n = 4, 6; X = Cl, Br) with two-electron monodentate P-donors like phosphines or phosphites or monodenate N-donors like pyridine-derived heterocyclic amines gave mononuclear Rh(III) complexes of piano-stool type [(C5Me4CnF2n+1)RhX2L] (L = two-eletron donor). Crystal structure of [(h5-C5Me4C4F9)Rh(PPri3)Cl2] was determined by X-ray diffraction. In contrast to their Cp* analogs, the pyridine complexes were stable in solution at room temperature. Cleavage of a double m-halo bridge in complexes [(C5Me4CnF2n+1)RhX2]2 (n = 4, 6; X = Cl, Br) with two-electron monodentate P-donors like phosphines or phosphites or monodenate N-donors like pyridine-derived heterocyclic amines gave mononuclear Rh(III) complexes of piano-stool type [(C5Me4CnF2n+1)RhX2L] (L = two-eletron donor). Crystal structure of [(h5-C5Me4C4F9)Rh(PPri3)Cl2] was determined by X-ray diffraction. In contrast to their Cp* analogs, the pyridine complexes were stable in solution at room temperature. (en)
Title	Tetramethyl(perfluoroalkyl)cyclopentadienyl Rhodium(III) Complexes Containing Phosphorus and Nitrogen Monodentate Donors. Crystal Structure of [(h5-C5Me4C4F9)Rh(PPri3)Cl2] Tetramethyl(perfluoroalkyl)cyclopentadienyl Rhodium(III) Complexes Containing Phosphorus and Nitrogen Monodentate Donors. Crystal Structure of [(h5-C5Me4C4F9)Rh(PPri3)Cl2] (en) Tetramethyl(perfluoralkyl)cyklopentadienylrhodité komplexy obsahující fosforové a dusíkaté monodentátní donory. Krystalová struktura [(?5-C5Me4C4F9)Rh(PPri3)Cl2] (cs)
skos:prefLabel	Tetramethyl(perfluoroalkyl)cyclopentadienyl Rhodium(III) Complexes Containing Phosphorus and Nitrogen Monodentate Donors. Crystal Structure of [(h5-C5Me4C4F9)Rh(PPri3)Cl2] Tetramethyl(perfluoroalkyl)cyclopentadienyl Rhodium(III) Complexes Containing Phosphorus and Nitrogen Monodentate Donors. Crystal Structure of [(h5-C5Me4C4F9)Rh(PPri3)Cl2] (en) Tetramethyl(perfluoralkyl)cyklopentadienylrhodité komplexy obsahující fosforové a dusíkaté monodentátní donory. Krystalová struktura [(?5-C5Me4C4F9)Rh(PPri3)Cl2] (cs)
skos:notation	RIV/67985858:_____/07:00096230!RIV08-AV0-67985858
http://linked.open.../vavai/riv/strany	1557;1570
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(IAA4072203), P(LC06070), Z(AV0Z40720504)
http://linked.open...iv/cisloPeriodika	7
http://linked.open...vai/riv/dodaniDat	2008
http://linked.open...aciTvurceVysledku	Čermák, Jan Krupková, Alena Sýkora, Jan Žádný, Jaroslav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav chemických procesů AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	454898
http://linked.open...ai/riv/idVysledku	RIV/67985858:_____/07:00096230
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	fluorous cyclopentadienes; rhodium complexes; hindered ligand rotation (en)
http://linked.open.../riv/klicoveSlovo	fluorous cyclopentadienes rhodium complexes hindered ligand rotation
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[432FD9752678]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	9 (xsd:int)
http://linked.open...vavai/riv/projekt	Novel fluorophilic ligands for transition metal complexes based on polyfluorinated The structure and synthetic applications of transition metal complexes
http://linked.open...UplatneniVysledku	2007
http://linked.open...v/svazekPeriodika	692
http://linked.open...iv/tvurceVysledku	Císařová, I. Sýkora, Jan Krupková, Alena Nguyen Thi, T. H. Čermák, Jan Žádný, Jaroslav Lopatová, K. Vlachová, A. Šauliová, J.
http://linked.open...n/vavai/riv/zamer	Investigation of multiphase reacting systems for the design of processes important in synthesis and preparation of novel materials, in energy production and in environmental protection
issn	0022-328X
number of pages	14 (xsd:int)

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