About: Diphosphinoazine Rhodium(I) and Iridium(I) Complexes

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The first rhodium complexes of diphosphinoazines [{RhCl(1,2-h:5,6-h- CH=CHCH2CH2CH=CHCH2CH2 )}2{m-R2PCH2C(But)=NN=C(But)CH2PR2] (R = Ph, Cy, Pri) were prepared by cleavage of the bridge in chloro(cycloocta-1,5-diene)rhodium(I) dimer, the analogous iridium(I) complexes were also prepared for the first time. The X-ray structures of isostructural rhodium and iridium complexes with bis(dicyclohexylphosphino)pinacoloneazine were determined. Diphosphinoazine ligands in the complexes remained in (Z,Z) configuration bridging two RhCl(C8H12) units. The first rhodium complexes of diphosphinoazines [{RhCl(1,2-h:5,6-h- CH=CHCH2CH2CH=CHCH2CH2 )}2{m-R2PCH2C(But)=NN=C(But)CH2PR2] (R = Ph, Cy, Pri) were prepared by cleavage of the bridge in chloro(cycloocta-1,5-diene)rhodium(I) dimer, the analogous iridium(I) complexes were also prepared for the first time. The X-ray structures of isostructural rhodium and iridium complexes with bis(dicyclohexylphosphino)pinacoloneazine were determined. Diphosphinoazine ligands in the complexes remained in (Z,Z) configuration bridging two RhCl(C8H12) units. (en) Štěpením můstku chloro(cyclookta-1,5-dien)rhodného dimeru byly připraveny první komplexy rhodia s difosfinoaziny [{RhCl(1,2-h:5,6-h- CH=CHCH2CH2CH=CHCH2CH2 )}2{m-R2PCH2C(But)=NN=C(But)CH2PR2] (R = Ph, Cy, Pri), poprvé byly rovněž připraveny analogické komplexy iridia. Rentgenovou difrakcí byly určeny struktury isostrukturních rhodných a iridných komplexů s bis(dicyklohexylfosfino)pinakolonazinem. Difosfinoazinové ligandy v komplexech zůstávají v (Z,Z) konfiguraci a můstkují dvě RhCl(C8H12) jednotky. (cs)
Title	Diphosphinoazine Rhodium(I) and Iridium(I) Complexes Difosfinoazinové komplexy rhodia(I) a iridia(I) (cs) Diphosphinoazine Rhodium(I) and Iridium(I) Complexes (en)
skos:prefLabel	Diphosphinoazine Rhodium(I) and Iridium(I) Complexes Difosfinoazinové komplexy rhodia(I) a iridia(I) (cs) Diphosphinoazine Rhodium(I) and Iridium(I) Complexes (en)
skos:notation	RIV/67985858:_____/06:00049450!RIV07-AV0-67985858
http://linked.open.../vavai/riv/strany	197;206
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/01/0554), P(GA203/99/M037), Z(AV0Z40720504)
http://linked.open...iv/cisloPeriodika	2
http://linked.open...vai/riv/dodaniDat	2007
http://linked.open...aciTvurceVysledku	Čermák, Jan Pošta, Martin
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav chemických procesů AV ČR, v. v. i.
http://linked.open...dnocenehoVysledku	471785
http://linked.open...ai/riv/idVysledku	RIV/67985858:_____/06:00049450
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	diphosphinoazines; rhodium complexes; iridium complexes (en)
http://linked.open.../riv/klicoveSlovo	iridium complexes rhodium complexes diphosphinoazines
http://linked.open...odStatuVydavatele	CZ - Česká republika
http://linked.open...ontrolniKodProRIV	[9EEF2C63FBF8]
http://linked.open...i/riv/nazevZdroje	Collection of Czechoslovak Chemical Communications
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Centre of molecular and crystal structures New highly active catalysts for the Heck reaction
http://linked.open...UplatneniVysledku	2006
http://linked.open...v/svazekPeriodika	71
http://linked.open...iv/tvurceVysledku	Císařová, I. Čermák, Jan Pošta, Martin Vojtíšek, P.
http://linked.open...n/vavai/riv/zamer	Investigation of multiphase reacting systems for the design of processes important in synthesis and preparation of novel materials, in energy production and in environmental protection
issn	0010-0765
number of pages	10 (xsd:int)

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