About: Thermodynamic properties of scorodite and parascorodite (FeAsO4 center dot 2H(2)O), kankite (FeAsO4 center dot 3.5H(2)O), and FeAsO4     Goto   Sponge   NotDistinct   Permalink

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  • Iron arsenates, especially scorodite (FeAsO42H2O), are the usual phases of choice for arsenic immobilization in waste forms of variable origin. The thermodynamic properties of this phase, necessary for the prediction of its dissolution or precipitation, have been usually constrained by solubility experiments. Here, we measured the thermodynamic properties of scorodite, its polymorph parascorodite, the mineral kaňkite (FeAsO43.5H2O), and the anhydrous FeAsO4 by a combination of calorimetric techniques, thus avoiding the inherent uncertainties of the solubility experiments.
  • Iron arsenates, especially scorodite (FeAsO42H2O), are the usual phases of choice for arsenic immobilization in waste forms of variable origin. The thermodynamic properties of this phase, necessary for the prediction of its dissolution or precipitation, have been usually constrained by solubility experiments. Here, we measured the thermodynamic properties of scorodite, its polymorph parascorodite, the mineral kaňkite (FeAsO43.5H2O), and the anhydrous FeAsO4 by a combination of calorimetric techniques, thus avoiding the inherent uncertainties of the solubility experiments. (en)
Title
  • Thermodynamic properties of scorodite and parascorodite (FeAsO4 center dot 2H(2)O), kankite (FeAsO4 center dot 3.5H(2)O), and FeAsO4
  • Thermodynamic properties of scorodite and parascorodite (FeAsO4 center dot 2H(2)O), kankite (FeAsO4 center dot 3.5H(2)O), and FeAsO4 (en)
skos:prefLabel
  • Thermodynamic properties of scorodite and parascorodite (FeAsO4 center dot 2H(2)O), kankite (FeAsO4 center dot 3.5H(2)O), and FeAsO4
  • Thermodynamic properties of scorodite and parascorodite (FeAsO4 center dot 2H(2)O), kankite (FeAsO4 center dot 3.5H(2)O), and FeAsO4 (en)
skos:notation
  • RIV/67985831:_____/12:00377319!RIV13-AV0-67985831
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, Z(AV0Z30130516), Z(MSM0021620855)
http://linked.open...iv/cisloPeriodika
  • April
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 174301
http://linked.open...ai/riv/idVysledku
  • RIV/67985831:_____/12:00377319
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • scorodite; ferric arsenates; formation enthalpy; entropy; solubility (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [049AE4549A46]
http://linked.open...i/riv/nazevZdroje
  • Hydrometallurgy
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 117/118
http://linked.open...iv/tvurceVysledku
  • Majzlan, J.
  • Plášil, J.
  • Drahota, P.
  • Filippi, Michal
  • Boerio-Goates, J.
  • Grevel, K.-D.
  • Kahl, W.-A.
  • Woodfield, B. F.
http://linked.open...ain/vavai/riv/wos
  • 000303486500007
http://linked.open...n/vavai/riv/zamer
issn
  • 0304-386X
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.hydromet.2012.02.002
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