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Description
| - Phase relations within the system Fe–Nb–S were studied experimentally by the technique of evacuated silica glass tubes in the temperature interval 400–1000°C. The dominant field in the system is a broad solid-solution FexNbyyS22 (0 < x < 0.5, 1.0 < y < 1.4) that includes the composition of the mineral edgarite. Also, it forms stable assemblages with pyrrhotite and pyrite. The iron sulfides dissolve limited amounts of Nb: pyrrhotite dissolves up to 1.13 at.% Nb, and pyrite, only 0.02 at.% Nb. We refined the crystal structure of five samples of the FexNbyS2 solid solution, and established the relation between the unit-cell volume and Fe/(Fe + Nb). The occurrence of edgarite can be expected in associations with other sulfides crystallizing under extremely low fugacity of oxygen.
- Phase relations within the system Fe–Nb–S were studied experimentally by the technique of evacuated silica glass tubes in the temperature interval 400–1000°C. The dominant field in the system is a broad solid-solution FexNbyyS22 (0 < x < 0.5, 1.0 < y < 1.4) that includes the composition of the mineral edgarite. Also, it forms stable assemblages with pyrrhotite and pyrite. The iron sulfides dissolve limited amounts of Nb: pyrrhotite dissolves up to 1.13 at.% Nb, and pyrite, only 0.02 at.% Nb. We refined the crystal structure of five samples of the FexNbyS2 solid solution, and established the relation between the unit-cell volume and Fe/(Fe + Nb). The occurrence of edgarite can be expected in associations with other sulfides crystallizing under extremely low fugacity of oxygen. (en)
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Title
| - The system Fe-Nb-S and its geological implications
- The system Fe-Nb-S and its geological implications (en)
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skos:prefLabel
| - The system Fe-Nb-S and its geological implications
- The system Fe-Nb-S and its geological implications (en)
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skos:notation
| - RIV/67985831:_____/10:00356123!RIV11-GA0-67985831
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - I, P(GA205/08/0122), Z(AV0Z10100521), Z(AV0Z30130516), Z(MZP0002579801)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/67985831:_____/10:00356123
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - phase relations; edgarite; FexNbyS2 solid solution; Nb sulfides; system Fe-Nb-S; crystal-structure refinements (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Hybler, Jiří
- Böhmová, Vlasta
- Drábek, M.
- Rieder, M.
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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