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  • Phase relations within the system Fe–Nb–S were studied experimentally by the technique of evacuated silica glass tubes in the temperature interval 400–1000°C. The dominant field in the system is a broad solid-solution FexNbyyS22 (0 < x < 0.5, 1.0 < y < 1.4) that includes the composition of the mineral edgarite. Also, it forms stable assemblages with pyrrhotite and pyrite. The iron sulfides dissolve limited amounts of Nb: pyrrhotite dissolves up to 1.13 at.% Nb, and pyrite, only 0.02 at.% Nb. We refined the crystal structure of five samples of the FexNbyS2 solid solution, and established the relation between the unit-cell volume and Fe/(Fe + Nb). The occurrence of edgarite can be expected in associations with other sulfides crystallizing under extremely low fugacity of oxygen.
  • Phase relations within the system Fe–Nb–S were studied experimentally by the technique of evacuated silica glass tubes in the temperature interval 400–1000°C. The dominant field in the system is a broad solid-solution FexNbyyS22 (0 < x < 0.5, 1.0 < y < 1.4) that includes the composition of the mineral edgarite. Also, it forms stable assemblages with pyrrhotite and pyrite. The iron sulfides dissolve limited amounts of Nb: pyrrhotite dissolves up to 1.13 at.% Nb, and pyrite, only 0.02 at.% Nb. We refined the crystal structure of five samples of the FexNbyS2 solid solution, and established the relation between the unit-cell volume and Fe/(Fe + Nb). The occurrence of edgarite can be expected in associations with other sulfides crystallizing under extremely low fugacity of oxygen. (en)
Title
  • The system Fe-Nb-S and its geological implications
  • The system Fe-Nb-S and its geological implications (en)
skos:prefLabel
  • The system Fe-Nb-S and its geological implications
  • The system Fe-Nb-S and its geological implications (en)
skos:notation
  • RIV/67985831:_____/10:00356123!RIV11-GA0-67985831
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • I, P(GA205/08/0122), Z(AV0Z10100521), Z(AV0Z30130516), Z(MZP0002579801)
http://linked.open...iv/cisloPeriodika
  • 5
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 291605
http://linked.open...ai/riv/idVysledku
  • RIV/67985831:_____/10:00356123
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • phase relations; edgarite; FexNbyS2 solid solution; Nb sulfides; system Fe-Nb-S; crystal-structure refinements (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CA - Kanada
http://linked.open...ontrolniKodProRIV
  • [43B703C56CA4]
http://linked.open...i/riv/nazevZdroje
  • Canadian Mineralogist
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 48
http://linked.open...iv/tvurceVysledku
  • Hybler, Jiří
  • Böhmová, Vlasta
  • Drábek, M.
  • Rieder, M.
http://linked.open...ain/vavai/riv/wos
  • 000283870800003
http://linked.open...n/vavai/riv/zamer
issn
  • 0008-4476
number of pages
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