About: Amorphous Aluminum Hydroxide Control on Sulfate and Phosphate in Sediment-Solution Systems     Goto   Sponge   NotDistinct   Permalink

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  • We experimentally determined the adsorption characteristics of natural, freshly precipitated Al(OH)3 for SO4 and PO4. The fresh Al precipitate occurred in stream sediment of Jachymov Stream (Czech Republic). The Al-rich sediment strongly adsorbed added PO4 prior to acidification experiment; this sorbed PO4 was released only after substantial dissolution of the sediment, at pH 3.67. Sorption of P by Al(OH)3 appears to be an important control on dissolved PO4 concentration in surface waters, unless there is a large excess of PO4. Acidification of the sediment-solution system caused protonation of the sediment surface, thereby increasing the adsorption capacity for SO4. Maximum SO4 adsorption occurred at pH 4.2, below which dissolution of the sediment offset the increasing anion adsorption capacity, and formation of AISO4 + inhibited the increasing SO4 adsorption capacity. This research demonstrates that there are important pH thresholds for anion adsorption in freshwaters
  • We experimentally determined the adsorption characteristics of natural, freshly precipitated Al(OH)3 for SO4 and PO4. The fresh Al precipitate occurred in stream sediment of Jachymov Stream (Czech Republic). The Al-rich sediment strongly adsorbed added PO4 prior to acidification experiment; this sorbed PO4 was released only after substantial dissolution of the sediment, at pH 3.67. Sorption of P by Al(OH)3 appears to be an important control on dissolved PO4 concentration in surface waters, unless there is a large excess of PO4. Acidification of the sediment-solution system caused protonation of the sediment surface, thereby increasing the adsorption capacity for SO4. Maximum SO4 adsorption occurred at pH 4.2, below which dissolution of the sediment offset the increasing anion adsorption capacity, and formation of AISO4 + inhibited the increasing SO4 adsorption capacity. This research demonstrates that there are important pH thresholds for anion adsorption in freshwaters (en)
Title
  • Amorphous Aluminum Hydroxide Control on Sulfate and Phosphate in Sediment-Solution Systems
  • Amorphous Aluminum Hydroxide Control on Sulfate and Phosphate in Sediment-Solution Systems (en)
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  • Amorphous Aluminum Hydroxide Control on Sulfate and Phosphate in Sediment-Solution Systems
  • Amorphous Aluminum Hydroxide Control on Sulfate and Phosphate in Sediment-Solution Systems (en)
skos:notation
  • RIV/67985831:_____/09:00326225!RIV13-AV0-67985831
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  • P(ME 840), Z(AV0Z30130516), Z(MZP0002579801)
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  • 1-4
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  • 302651
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  • RIV/67985831:_____/09:00326225
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  • adsorption; oligotrophy; Al precipitates; anions; acidification; alkalization (en)
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  • NL - Nizozemsko
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  • [CD90FCD870B6]
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  • Water, Air and Soil Pollution
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  • 201
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  • Fernandez, I. J.
  • Norton, S. A.
  • Rohovec, Jan
  • Navrátil, T.
  • Amirbahman, A.
http://linked.open...ain/vavai/riv/wos
  • 000266928600009
http://linked.open...n/vavai/riv/zamer
issn
  • 0049-6979
number of pages
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  • 10.1007/s11270-008-9929-z
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