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Description
| - Catalytically active, stable, and mechanically durable solid K/Al2O3 catalysts for the transesterification of rapeseed oil with methanol was studied. In a batch reactor, high catalytic activity was accompanied by leaching of K species, caused by glycerol, and mechanical destruction of the solid catalyst as a result of contact with the stirrer. In a fixed-bed reactor, some leaching of K species into the liquid phases was also observed, but approached 0 during 30 h of time-on-stream; the activity of the K/Al2O3 catalyst (83% ester yield) was stable for 100 h of time-on-stream and no mechanical destruction of the catalyst was observed. The populations of K2O and K-O-Al species for fresh and used K/Al2O3 catalysts were compared using Fourier transform infrared spectroscopy. It was found that some K2O species leached into the liquid phases at the beginning of the reaction.
- Catalytically active, stable, and mechanically durable solid K/Al2O3 catalysts for the transesterification of rapeseed oil with methanol was studied. In a batch reactor, high catalytic activity was accompanied by leaching of K species, caused by glycerol, and mechanical destruction of the solid catalyst as a result of contact with the stirrer. In a fixed-bed reactor, some leaching of K species into the liquid phases was also observed, but approached 0 during 30 h of time-on-stream; the activity of the K/Al2O3 catalyst (83% ester yield) was stable for 100 h of time-on-stream and no mechanical destruction of the catalyst was observed. The populations of K2O and K-O-Al species for fresh and used K/Al2O3 catalysts were compared using Fourier transform infrared spectroscopy. It was found that some K2O species leached into the liquid phases at the beginning of the reaction. (en)
- Catalytically active, stable, and mechanically durable solid K/Al2O3 catalysts for the transesterification of rapeseed oil with methanol was studied. In a batch reactor, high catalytic activity was accompanied by leaching of K species, caused by glycerol, and mechanical destruction of the solid catalyst as a result of contact with the stirrer. In a fixed-bed reactor, some leaching of K species into the liquid phases was also observed, but approached 0 during 30 h of time-on-stream; the activity of the K/Al2O3 catalyst (83% ester yield) was stable for 100 h of time-on-stream and no mechanical destruction of the catalyst was observed. The populations of K2O and K-O-Al species for fresh and used K/Al2O3 catalysts were compared using Fourier transform infrared spectroscopy. It was found that some K2O species leached into the liquid phases at the beginning of the reaction. (cs)
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Title
| - Aspects of stability of K/Al2O3 catalysts for the transesterification of rapeseed oil in batch and fixed-bed reactors
- Aspects of stability of K/Al2O3 catalysts for the transesterification of rapeseed oil in batch and fixed-bed reactors (en)
- Aspects of stability of K/Al2O3 catalysts for the transesterification of rapeseed oil in batch and fixed-bed reactors (cs)
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skos:prefLabel
| - Aspects of stability of K/Al2O3 catalysts for the transesterification of rapeseed oil in batch and fixed-bed reactors
- Aspects of stability of K/Al2O3 catalysts for the transesterification of rapeseed oil in batch and fixed-bed reactors (en)
- Aspects of stability of K/Al2O3 catalysts for the transesterification of rapeseed oil in batch and fixed-bed reactors (cs)
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skos:notation
| - RIV/62243136:_____/14:GACR11CL!RIV15-GA0-62243136
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/62243136:_____/14:GACR11CL
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Rapeseed oil, Transesterification, Fixed-bed reactor, Potassium, Alumina, Supported catalyst (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - CN - Čínská lidová republika
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Chinese Journal of Catalysis
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Kubička, David
- Smoláková, Lucie
- Čapek, Libor
- Hájek, Martin
- Kutálek, Petr
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1016/S1872-2067(14)60054-1
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