About: Aspects of stability of K/Al2O3 catalysts for the transesterification of rapeseed oil in batch and fixed-bed reactors     Goto   Sponge   NotDistinct   Permalink

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  • Catalytically active, stable, and mechanically durable solid K/Al2O3 catalysts for the transesterification of rapeseed oil with methanol was studied. In a batch reactor, high catalytic activity was accompanied by leaching of K species, caused by glycerol, and mechanical destruction of the solid catalyst as a result of contact with the stirrer. In a fixed-bed reactor, some leaching of K species into the liquid phases was also observed, but approached 0 during 30 h of time-on-stream; the activity of the K/Al2O3 catalyst (83% ester yield) was stable for 100 h of time-on-stream and no mechanical destruction of the catalyst was observed. The populations of K2O and K-O-Al species for fresh and used K/Al2O3 catalysts were compared using Fourier transform infrared spectroscopy. It was found that some K2O species leached into the liquid phases at the beginning of the reaction.
  • Catalytically active, stable, and mechanically durable solid K/Al2O3 catalysts for the transesterification of rapeseed oil with methanol was studied. In a batch reactor, high catalytic activity was accompanied by leaching of K species, caused by glycerol, and mechanical destruction of the solid catalyst as a result of contact with the stirrer. In a fixed-bed reactor, some leaching of K species into the liquid phases was also observed, but approached 0 during 30 h of time-on-stream; the activity of the K/Al2O3 catalyst (83% ester yield) was stable for 100 h of time-on-stream and no mechanical destruction of the catalyst was observed. The populations of K2O and K-O-Al species for fresh and used K/Al2O3 catalysts were compared using Fourier transform infrared spectroscopy. It was found that some K2O species leached into the liquid phases at the beginning of the reaction. (en)
  • Catalytically active, stable, and mechanically durable solid K/Al2O3 catalysts for the transesterification of rapeseed oil with methanol was studied. In a batch reactor, high catalytic activity was accompanied by leaching of K species, caused by glycerol, and mechanical destruction of the solid catalyst as a result of contact with the stirrer. In a fixed-bed reactor, some leaching of K species into the liquid phases was also observed, but approached 0 during 30 h of time-on-stream; the activity of the K/Al2O3 catalyst (83% ester yield) was stable for 100 h of time-on-stream and no mechanical destruction of the catalyst was observed. The populations of K2O and K-O-Al species for fresh and used K/Al2O3 catalysts were compared using Fourier transform infrared spectroscopy. It was found that some K2O species leached into the liquid phases at the beginning of the reaction. (cs)
Title
  • Aspects of stability of K/Al2O3 catalysts for the transesterification of rapeseed oil in batch and fixed-bed reactors
  • Aspects of stability of K/Al2O3 catalysts for the transesterification of rapeseed oil in batch and fixed-bed reactors (en)
  • Aspects of stability of K/Al2O3 catalysts for the transesterification of rapeseed oil in batch and fixed-bed reactors (cs)
skos:prefLabel
  • Aspects of stability of K/Al2O3 catalysts for the transesterification of rapeseed oil in batch and fixed-bed reactors
  • Aspects of stability of K/Al2O3 catalysts for the transesterification of rapeseed oil in batch and fixed-bed reactors (en)
  • Aspects of stability of K/Al2O3 catalysts for the transesterification of rapeseed oil in batch and fixed-bed reactors (cs)
skos:notation
  • RIV/62243136:_____/14:GACR11CL!RIV15-GA0-62243136
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GAP106/11/0773)
http://linked.open...iv/cisloPeriodika
  • 7
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 4193
http://linked.open...ai/riv/idVysledku
  • RIV/62243136:_____/14:GACR11CL
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Rapeseed oil, Transesterification, Fixed-bed reactor, Potassium, Alumina, Supported catalyst (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CN - Čínská lidová republika
http://linked.open...ontrolniKodProRIV
  • [DCBDED861C7D]
http://linked.open...i/riv/nazevZdroje
  • Chinese Journal of Catalysis
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 35
http://linked.open...iv/tvurceVysledku
  • Kubička, David
  • Smoláková, Lucie
  • Čapek, Libor
  • Hájek, Martin
  • Kutálek, Petr
http://linked.open...ain/vavai/riv/wos
  • 000338913700015
issn
  • 0253-9837
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/S1872-2067(14)60054-1
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