About: Dinucleating role of a strong hydrogen bond in crystal structure of [N(C4H9)4]{[VO(HO2)(O2)(phen)][VO(O2)2(phen)]}?3H2O2?H2O     Goto   Sponge   NotDistinct   Permalink

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Description
  • Diperoxidovanadium complex with 1,10-phenanthroline, [N(C4H9)4]{[VO(HO2)(O2)(phen)][VO(O2)2(phen)]}?3H2O2? H2O (1), has been prepared and characterized by infrared, Raman and 51V NMR spectra. X-ray structure analysis revealed the presence of dinuclear anion in 1 in which the [VO(HO2)(O2)(phen)] and [VO(O2)2(phen)]? entities are connected via a short, strong hydrogen bond formed between hydrogenperoxido (HO2?) and peroxido groups. Moreover, the crystal structure is stabilized by the stacking interactions between 1,10-phenanthroline ligands. We have attempted to estimate the binding energy of hydrogen bond in the dinuclear anion as well as the binding energy between stacked complex entities based on gas-phase quantum chemistry calculations.
  • Diperoxidovanadium complex with 1,10-phenanthroline, [N(C4H9)4]{[VO(HO2)(O2)(phen)][VO(O2)2(phen)]}?3H2O2? H2O (1), has been prepared and characterized by infrared, Raman and 51V NMR spectra. X-ray structure analysis revealed the presence of dinuclear anion in 1 in which the [VO(HO2)(O2)(phen)] and [VO(O2)2(phen)]? entities are connected via a short, strong hydrogen bond formed between hydrogenperoxido (HO2?) and peroxido groups. Moreover, the crystal structure is stabilized by the stacking interactions between 1,10-phenanthroline ligands. We have attempted to estimate the binding energy of hydrogen bond in the dinuclear anion as well as the binding energy between stacked complex entities based on gas-phase quantum chemistry calculations. (en)
Title
  • Dinucleating role of a strong hydrogen bond in crystal structure of [N(C4H9)4]{[VO(HO2)(O2)(phen)][VO(O2)2(phen)]}?3H2O2?H2O
  • Dinucleating role of a strong hydrogen bond in crystal structure of [N(C4H9)4]{[VO(HO2)(O2)(phen)][VO(O2)2(phen)]}?3H2O2?H2O (en)
skos:prefLabel
  • Dinucleating role of a strong hydrogen bond in crystal structure of [N(C4H9)4]{[VO(HO2)(O2)(phen)][VO(O2)2(phen)]}?3H2O2?H2O
  • Dinucleating role of a strong hydrogen bond in crystal structure of [N(C4H9)4]{[VO(HO2)(O2)(phen)][VO(O2)2(phen)]}?3H2O2?H2O (en)
skos:notation
  • RIV/62157124:16370/12:43871555!RIV13-MSM-16370___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • V
http://linked.open...iv/cisloPeriodika
  • October
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 131390
http://linked.open...ai/riv/idVysledku
  • RIV/62157124:16370/12:43871555
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Weak interactions; Charge-assisted hydrogen bond; Peroxido ligand; 1,10-phenanthroline ligand; Vanadium(V) complex (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [E75C07B4C105]
http://linked.open...i/riv/nazevZdroje
  • Inorganic Chemistry Communications
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 24
http://linked.open...iv/tvurceVysledku
  • Pavelčík, František
  • Chrappová, Jana
  • Schwendt, Peter
  • Šimunek, Ján
  • Šimuneková, Mária
  • Žák, Zdirad
http://linked.open...ain/vavai/riv/wos
  • 000311066000029
issn
  • 1387-7003
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.inoche.2012.08.003
http://localhost/t...ganizacniJednotka
  • 16370
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