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rdf:type
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Description
| - Diperoxidovanadium complex with 1,10-phenanthroline, [N(C4H9)4]{[VO(HO2)(O2)(phen)][VO(O2)2(phen)]}?3H2O2? H2O (1), has been prepared and characterized by infrared, Raman and 51V NMR spectra. X-ray structure analysis revealed the presence of dinuclear anion in 1 in which the [VO(HO2)(O2)(phen)] and [VO(O2)2(phen)]? entities are connected via a short, strong hydrogen bond formed between hydrogenperoxido (HO2?) and peroxido groups. Moreover, the crystal structure is stabilized by the stacking interactions between 1,10-phenanthroline ligands. We have attempted to estimate the binding energy of hydrogen bond in the dinuclear anion as well as the binding energy between stacked complex entities based on gas-phase quantum chemistry calculations.
- Diperoxidovanadium complex with 1,10-phenanthroline, [N(C4H9)4]{[VO(HO2)(O2)(phen)][VO(O2)2(phen)]}?3H2O2? H2O (1), has been prepared and characterized by infrared, Raman and 51V NMR spectra. X-ray structure analysis revealed the presence of dinuclear anion in 1 in which the [VO(HO2)(O2)(phen)] and [VO(O2)2(phen)]? entities are connected via a short, strong hydrogen bond formed between hydrogenperoxido (HO2?) and peroxido groups. Moreover, the crystal structure is stabilized by the stacking interactions between 1,10-phenanthroline ligands. We have attempted to estimate the binding energy of hydrogen bond in the dinuclear anion as well as the binding energy between stacked complex entities based on gas-phase quantum chemistry calculations. (en)
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Title
| - Dinucleating role of a strong hydrogen bond in crystal structure of [N(C4H9)4]{[VO(HO2)(O2)(phen)][VO(O2)2(phen)]}?3H2O2?H2O
- Dinucleating role of a strong hydrogen bond in crystal structure of [N(C4H9)4]{[VO(HO2)(O2)(phen)][VO(O2)2(phen)]}?3H2O2?H2O (en)
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skos:prefLabel
| - Dinucleating role of a strong hydrogen bond in crystal structure of [N(C4H9)4]{[VO(HO2)(O2)(phen)][VO(O2)2(phen)]}?3H2O2?H2O
- Dinucleating role of a strong hydrogen bond in crystal structure of [N(C4H9)4]{[VO(HO2)(O2)(phen)][VO(O2)2(phen)]}?3H2O2?H2O (en)
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skos:notation
| - RIV/62157124:16370/12:43871555!RIV13-MSM-16370___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/62157124:16370/12:43871555
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Weak interactions; Charge-assisted hydrogen bond; Peroxido ligand; 1,10-phenanthroline ligand; Vanadium(V) complex (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Inorganic Chemistry Communications
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Pavelčík, František
- Chrappová, Jana
- Schwendt, Peter
- Šimunek, Ján
- Šimuneková, Mária
- Žák, Zdirad
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1016/j.inoche.2012.08.003
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http://localhost/t...ganizacniJednotka
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