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  • The influence of the addition of polyethylene glycol (PEG) to the background electrolyte on the capillary zone electrophoretic (CZE) separation of alkylpyridines was studied. It was found out that interactions between polyethylene glycol chains and protonized pyridine bases cause the increasing of the resolution. The separation of a model mixture of pyridine, all isomers of methylpyridine, and some other alkyl and aryl derivatives was performed. The separation was complete except for some dimethylpyridines. The influence of the co-ion was discussed, too. Polyethylene glycol solution as a separation medium was used for the capillary zone electrophoretic determination of pyridine bases in an industrial mixture. (C) 1999 Elsevier Science B.V. All rights reserved.
  • The influence of the addition of polyethylene glycol (PEG) to the background electrolyte on the capillary zone electrophoretic (CZE) separation of alkylpyridines was studied. It was found out that interactions between polyethylene glycol chains and protonized pyridine bases cause the increasing of the resolution. The separation of a model mixture of pyridine, all isomers of methylpyridine, and some other alkyl and aryl derivatives was performed. The separation was complete except for some dimethylpyridines. The influence of the co-ion was discussed, too. Polyethylene glycol solution as a separation medium was used for the capillary zone electrophoretic determination of pyridine bases in an industrial mixture. (C) 1999 Elsevier Science B.V. All rights reserved. (en)
Title
  • Polyethylene glycol as a separation medium for capillary zone electrophoretic analysis of pyridine derivatives
  • Polyethylene glycol as a separation medium for capillary zone electrophoretic analysis of pyridine derivatives (en)
skos:prefLabel
  • Polyethylene glycol as a separation medium for capillary zone electrophoretic analysis of pyridine derivatives
  • Polyethylene glycol as a separation medium for capillary zone electrophoretic analysis of pyridine derivatives (en)
skos:notation
  • RIV/61989592:15310/99:00000742!RIV/2000/MSM/153100
http://linked.open.../vavai/riv/strany
  • 89
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(VS96021), Z(MSM 153100013)
http://linked.open...iv/cisloPeriodika
  • 1-2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
  • Barták, Petr
  • Stránský, Zdeněk
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 749940
http://linked.open...ai/riv/idVysledku
  • RIV/61989592:15310/99:00000742
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • ALKALINE-EARTH METAL; CATIONS (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [4D6E6D784166]
http://linked.open...i/riv/nazevZdroje
  • Journal of Chromatography A: Symposium Volumes
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 838
http://linked.open...iv/tvurceVysledku
  • Barták, Petr
  • Bednář, Petr
  • Stránský, Zdeněk
  • Adamovsky, P.
http://linked.open...n/vavai/riv/zamer
issn
  • 0021-9673
number of pages
http://localhost/t...ganizacniJednotka
  • 15310
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