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Description
| - A series of square-planar nickel(II) benzylpiperazine-dithiocarbamato (bpdtc; 1-4) and thiomorpholinedithiocarbamato (tmdtc; 5-8) complexes of the composition [NiX(ndtc)(PPh3)] (X symbolizes Cl for I and 5, Br for 2 and 6, I for 3 and 7, or NCS for 4 and 8) was prepared and thoroughly characterized by elemental analysis, UV-Vis, IR and NMR spectroscopy, mass spectrometry, molar conductivity and magnetochemical measurements, and by single-crystal X-ray analysis (for complex 1). The solution behaviour study of selected representatives (1, 4, 5 and 8) in various solvents (acetone, acetonitrile, methanol (MeOH), N,N'-dimethylformamide (DMF), chloroform, nitromethane, dimethyl sulfoxide (DMSO), MeOH/water mixture (1:1 v/v)) by a combination of NMR and UV-Vis spectroscopy, mass spectrometry and single-crystal X-ray analysis showed that the complexes decompose back to the synthetic precursors, involving the [Ni(ndtc)(2)] species, in DMF and DMSO, while they dissolve without a change in their composition in the remaining solvents.
- A series of square-planar nickel(II) benzylpiperazine-dithiocarbamato (bpdtc; 1-4) and thiomorpholinedithiocarbamato (tmdtc; 5-8) complexes of the composition [NiX(ndtc)(PPh3)] (X symbolizes Cl for I and 5, Br for 2 and 6, I for 3 and 7, or NCS for 4 and 8) was prepared and thoroughly characterized by elemental analysis, UV-Vis, IR and NMR spectroscopy, mass spectrometry, molar conductivity and magnetochemical measurements, and by single-crystal X-ray analysis (for complex 1). The solution behaviour study of selected representatives (1, 4, 5 and 8) in various solvents (acetone, acetonitrile, methanol (MeOH), N,N'-dimethylformamide (DMF), chloroform, nitromethane, dimethyl sulfoxide (DMSO), MeOH/water mixture (1:1 v/v)) by a combination of NMR and UV-Vis spectroscopy, mass spectrometry and single-crystal X-ray analysis showed that the complexes decompose back to the synthetic precursors, involving the [Ni(ndtc)(2)] species, in DMF and DMSO, while they dissolve without a change in their composition in the remaining solvents. (en)
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Title
| - Effect of diverse solvents on the composition and structure of mixed-ligand nickel(II) dithiocarbamates: [NiX(ndtc)(PPh3)]
- Effect of diverse solvents on the composition and structure of mixed-ligand nickel(II) dithiocarbamates: [NiX(ndtc)(PPh3)] (en)
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skos:prefLabel
| - Effect of diverse solvents on the composition and structure of mixed-ligand nickel(II) dithiocarbamates: [NiX(ndtc)(PPh3)]
- Effect of diverse solvents on the composition and structure of mixed-ligand nickel(II) dithiocarbamates: [NiX(ndtc)(PPh3)] (en)
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skos:notation
| - RIV/61989592:15310/14:33152282!RIV15-MSM-15310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(ED2.1.00/03.0058), P(EE2.3.20.0017), S
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61989592:15310/14:33152282
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - Mass spectrometry; NMR; Solution study; Crystal structure; Dithiocarbamate; Nickel(II) complexes (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - GB - Spojené království Velké Británie a Severního Irska
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Trávníček, Zdeněk
- Štarha, Pavel
- Drahoš, Bohuslav
- Pastorek, Richard
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http://linked.open...ain/vavai/riv/wos
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issn
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number of pages
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http://bibframe.org/vocab/doi
| - 10.1016/j.poly.2013.11.041
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http://localhost/t...ganizacniJednotka
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