About: Mossbauer investigation of the reaction of ferrate(VI) with sulfamethoxazole and aniline in alkaline medium

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About: Mossbauer investigation of the reaction of ferrate(VI) with sulfamethoxazole and aniline in alkaline medium Goto Sponge NotDistinct Permalink

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Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://download.springer.com/static/pdf/349/art%253A10.1007%252Fs10751-013-0819-4.pdf?auth66=1424769455_3d685a471239444afb706dea4d457620&ext=.pdf
Description	Mechanisms on the oxidation of sulfamethoxazole (SMX) and aniline by ferrate(VI) (FeVIO4 2?, Fe(VI)) in alkaline medium suggested the formation of Fe(VI)-SMX or Fe(VI)-aniline intermediates, respectively. Fe(V) and Fe(IV) as other intermediate iron species have also been proposed in the mechanism. In this paper, rapid freezeMössbauer spectroscopy was applied in rapidly frozen samples to explore intermediate iron species in the reactions of SMX and aniline with Fe(VI). In both reactions, Fe(VI)-SMX and Fe(VI)-aniline intermediates were not seen in second-minute time scale. Fe(V) and Fe(IV) were also not observed. Fe(III) was the only final species of the reactions. Mechanisms on the oxidation of sulfamethoxazole (SMX) and aniline by ferrate(VI) (FeVIO4 2?, Fe(VI)) in alkaline medium suggested the formation of Fe(VI)-SMX or Fe(VI)-aniline intermediates, respectively. Fe(V) and Fe(IV) as other intermediate iron species have also been proposed in the mechanism. In this paper, rapid freezeMössbauer spectroscopy was applied in rapidly frozen samples to explore intermediate iron species in the reactions of SMX and aniline with Fe(VI). In both reactions, Fe(VI)-SMX and Fe(VI)-aniline intermediates were not seen in second-minute time scale. Fe(V) and Fe(IV) were also not observed. Fe(III) was the only final species of the reactions. (en)
Title	Mossbauer investigation of the reaction of ferrate(VI) with sulfamethoxazole and aniline in alkaline medium Mossbauer investigation of the reaction of ferrate(VI) with sulfamethoxazole and aniline in alkaline medium (en)
skos:prefLabel	Mossbauer investigation of the reaction of ferrate(VI) with sulfamethoxazole and aniline in alkaline medium Mossbauer investigation of the reaction of ferrate(VI) with sulfamethoxazole and aniline in alkaline medium (en)
skos:notation	RIV/61989592:15310/14:33152270!RIV15-MSM-15310___
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(ED2.1.00/03.0058), P(EE2.3.20.0017), P(EE2.3.20.0056), P(EE2.3.20.0058), P(GPP108/11/P657)
http://linked.open...iv/cisloPeriodika	1-3
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Šišková, Karolína Zbořil, Radek Machala, Libor
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	30586
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/14:33152270
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	medium; alkaline; aniline; sulfamethoxazole; ferrateVI; reaction; investigation; Mossbauer (en)
http://linked.open.../riv/klicoveSlovo	ferrateVI reaction medium aniline investigation alkaline sulfamethoxazole Mossbauer
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[E33228D06483]
http://linked.open...i/riv/nazevZdroje	Hyperfine Interactions
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...vavai/riv/projekt	Building of research and education team in regional center of advanced technology and materials. Regional Centre of Advanced Technologies and Materials Research team development of the Regional Centre of Advanced Technologies and Materials Integration of Regional Centre of Advanced Technologies and Materials into International Networks of Nanotechnological and Optical Research. Preparation and characterization of new composite materials containing amino acids, iron oxides and silver or gold nanoparticles
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	224
http://linked.open...iv/tvurceVysledku	Zbořil, Radek Machala, Libor Machalová Šišková, Karolína Sharma, Virender K Hommonay, Zoltán
issn	0304-3843
number of pages	7 (xsd:int)
http://bibframe.org/vocab/doi	10.1007/s10751-013-0819-4
http://localhost/t...ganizacniJednotka	15310

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