About: Nanoliter Segmented-Flow Sampling Mass Spectrometry with Online Compartmentalization

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://pubs.acs.org/doi/pdf/10.1021/ac500365r
Description	We report a microfluidic device, using segmented flow in a two-phase system of immiscible liquids, which delivers aqueous droplets into a modified commercial mass spectrometer. The interface coupling the microfluidics to the mass spectrometer achieves up to 96% sample transfer efficiency to the vacuum chamber. Sample ionization is assisted by multipass infrared laser beam in the interface. The system achieves low femtomole detection limit's of several analytes ranging from drugs to proteins. Sample ionization in this segmented-flow sampling was found to be remarkably insensitive to the presence of buffer salts and other matrices. We report a microfluidic device, using segmented flow in a two-phase system of immiscible liquids, which delivers aqueous droplets into a modified commercial mass spectrometer. The interface coupling the microfluidics to the mass spectrometer achieves up to 96% sample transfer efficiency to the vacuum chamber. Sample ionization is assisted by multipass infrared laser beam in the interface. The system achieves low femtomole detection limit's of several analytes ranging from drugs to proteins. Sample ionization in this segmented-flow sampling was found to be remarkably insensitive to the presence of buffer salts and other matrices. (en)
Title	Nanoliter Segmented-Flow Sampling Mass Spectrometry with Online Compartmentalization Nanoliter Segmented-Flow Sampling Mass Spectrometry with Online Compartmentalization (en)
skos:prefLabel	Nanoliter Segmented-Flow Sampling Mass Spectrometry with Online Compartmentalization Nanoliter Segmented-Flow Sampling Mass Spectrometry with Online Compartmentalization (en)
skos:notation	RIV/61989592:15310/14:33151641!RIV15-MSM-15310___
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(ED2.1.00/03.0058), P(EE2.3.20.0058)
http://linked.open...iv/cisloPeriodika	7
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Fryčák, Petr
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	31517
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/14:33151641
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	plugs; interface; time; capillary; ionization; picoliter droplets; microfluidic system; liquid chromatography; electrospray ion-source (en)
http://linked.open.../riv/klicoveSlovo	ionization capillary plugs liquid chromatography time microfluidic system interface electrospray ion-source picoliter droplets
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[6B9EE1D7C1E9]
http://linked.open...i/riv/nazevZdroje	Analytical Chemistry
http://linked.open...in/vavai/riv/obor	CB
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	9 (xsd:int)
http://linked.open...vavai/riv/projekt	Regional Centre of Advanced Technologies and Materials Integration of Regional Centre of Advanced Technologies and Materials into International Networks of Nanotechnological and Optical Research.
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	86
http://linked.open...iv/tvurceVysledku	Schneider, Thomas Volný, Michael Fryčák, Petr Tureček, František Chiu, Daniel T. Hakimi, Bejan Liu, Dingsheng Rolfs, Joelle Yen, Gloria
http://linked.open...ain/vavai/riv/wos	000333776600054
issn	0003-2700
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1021/ac500365r
http://localhost/t...ganizacniJednotka	15310

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