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  • Hydroxyl free radical-induced oxidation of metformin was studied in aqueous solution as a function of the pH. Hydroxyl free radicals were generated by gamma radiolysis of water and the oxidation end-products were quantified by high-performance liquid chromatography coupled to mass spectrometry (HPLC/MS), as a function of the radiation dose. This work is a joint experimental and theoretical (DFT) approach that has paved the way towards a comprehensive rationalization of the one-electron mechanisms of MTF oxidation, as a function of the pH.
  • Hydroxyl free radical-induced oxidation of metformin was studied in aqueous solution as a function of the pH. Hydroxyl free radicals were generated by gamma radiolysis of water and the oxidation end-products were quantified by high-performance liquid chromatography coupled to mass spectrometry (HPLC/MS), as a function of the radiation dose. This work is a joint experimental and theoretical (DFT) approach that has paved the way towards a comprehensive rationalization of the one-electron mechanisms of MTF oxidation, as a function of the pH. (en)
Title
  • Mechanism of one-electron oxidation of metformin in aqueous solution
  • Mechanism of one-electron oxidation of metformin in aqueous solution (en)
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  • Mechanism of one-electron oxidation of metformin in aqueous solution
  • Mechanism of one-electron oxidation of metformin in aqueous solution (en)
skos:notation
  • RIV/61989592:15310/13:33148484!RIV14-MSM-15310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ED2.1.00/03.0058)
http://linked.open...iv/cisloPeriodika
  • 24
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
  • Trouillas, Patrick
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
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  • 87020
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  • RIV/61989592:15310/13:33148484
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  • radicals; products; quercetin; reactivity; induced diabetic-rats (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [A570899F0B46]
http://linked.open...i/riv/nazevZdroje
  • Physical Chemistry Chemical Physics
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  • 15
http://linked.open...iv/tvurceVysledku
  • Trouillas, Patrick
  • Bonnefont-Rousselot, Dominique
  • Collin, Fabrice
  • Gardes-Albertd, Monique
  • Jore, Daniel
  • Lazzaroni, Roberto
  • Marchetti, Catherine
http://linked.open...ain/vavai/riv/wos
  • 000319576500050
issn
  • 1463-9076
number of pages
http://bibframe.org/vocab/doi
  • 10.1039/c3cp50602a
http://localhost/t...ganizacniJednotka
  • 15310
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