About: Use of silver carbonate in the Wittig reaction

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	An efficient synthesis of olefins by the coupling of stabilized, semistabilized, and nonstabilized phosphorus ylides with various carbonyl compounds in the presence of silver carbonate is reported. Wittig olefination of aromatic, heteroaromatic, and aliphatic aldehydes (yields }63%) and a ketone (yield 42%) are demonstrated. These reactions proceed overnight at room temperature, under weakly basic conditions, and as such extend the applicability of the Wittig reaction to base-sensitive reactants. An efficient synthesis of olefins by the coupling of stabilized, semistabilized, and nonstabilized phosphorus ylides with various carbonyl compounds in the presence of silver carbonate is reported. Wittig olefination of aromatic, heteroaromatic, and aliphatic aldehydes (yields }63%) and a ketone (yield 42%) are demonstrated. These reactions proceed overnight at room temperature, under weakly basic conditions, and as such extend the applicability of the Wittig reaction to base-sensitive reactants. (en)
Title	Use of silver carbonate in the Wittig reaction Use of silver carbonate in the Wittig reaction (en)
skos:prefLabel	Use of silver carbonate in the Wittig reaction Use of silver carbonate in the Wittig reaction (en)
skos:notation	RIV/61989592:15310/13:33147711!RIV14-MSM-15310___
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(EE2.3.20.0009), P(EE2.4.31.0130)
http://linked.open...iv/cisloPeriodika	23
http://linked.open...vai/riv/dodaniDat	2014
http://linked.open...aciTvurceVysledku	Jedinák, Lukáš
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	113049
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/13:33147711
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Wittig, silver, silver carbonate (en)
http://linked.open.../riv/klicoveSlovo	Wittig silver carbonate silver
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[0483A2E1240D]
http://linked.open...i/riv/nazevZdroje	Journal of Organic Chemistry
http://linked.open...in/vavai/riv/obor	CC
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	8 (xsd:int)
http://linked.open...vavai/riv/projekt	Development and bolstering of cooperation among academic and commercial institutions with focuse on chemical and pharmaceutical research Combinatorial chemistry in research and education
http://linked.open...UplatneniVysledku	2013
http://linked.open...v/svazekPeriodika	78
http://linked.open...iv/tvurceVysledku	Boggess, Bill Fisher, Jed F Hesek, Dušan Jedinák, Lukáš Lee, Mijoon Mobashery, Shahriar Noll, Bruce C Rush, Latoya
http://linked.open...ain/vavai/riv/wos	000328231600065
issn	0022-3263
number of pages	5 (xsd:int)
http://bibframe.org/vocab/doi	10.1021/jo401972a
http://localhost/t...ganizacniJednotka	15310

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