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  • Liquid-phase exfoliation of graphite is a widely used method to obtain graphene nanosheets, and therefore the development of a simple and efficient exfoliation procedure remains challenging. Here, we present a one-step method of graphene exfoliation in lecithin/chloroform solution. The graphene nanosheets produced by the lecithin assisted exfoliation method were analyzed by microscopy techniques, including statistical analysis of atomic force microscopy (AFM) images and Raman spectroscopy, which both indicate the presence of few-layer graphene nanosheets, including substantial content of three-layer sheets. Molecular dynamics simulations on the time scale of 0.5+ mu s suggested that stability of the obtained colloid may originate from formation of lecithin reverse hemimicelles and micelles, which prevents the aggregation of exfoliated graphene flakes by entropic repulsion of the lipid hydrophobic chains.
  • Liquid-phase exfoliation of graphite is a widely used method to obtain graphene nanosheets, and therefore the development of a simple and efficient exfoliation procedure remains challenging. Here, we present a one-step method of graphene exfoliation in lecithin/chloroform solution. The graphene nanosheets produced by the lecithin assisted exfoliation method were analyzed by microscopy techniques, including statistical analysis of atomic force microscopy (AFM) images and Raman spectroscopy, which both indicate the presence of few-layer graphene nanosheets, including substantial content of three-layer sheets. Molecular dynamics simulations on the time scale of 0.5+ mu s suggested that stability of the obtained colloid may originate from formation of lecithin reverse hemimicelles and micelles, which prevents the aggregation of exfoliated graphene flakes by entropic repulsion of the lipid hydrophobic chains. (en)
Title
  • Lipid Enhanced Exfoliation for Production of Graphene Nanosheets
  • Lipid Enhanced Exfoliation for Production of Graphene Nanosheets (en)
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  • Lipid Enhanced Exfoliation for Production of Graphene Nanosheets
  • Lipid Enhanced Exfoliation for Production of Graphene Nanosheets (en)
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  • RIV/61989592:15310/13:33145709!RIV14-GA0-15310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ED2.1.00/03.0058), P(GAP208/10/1742), P(GBP208/12/G016), S
http://linked.open...iv/cisloPeriodika
  • 22
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  • 85056
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  • RIV/61989592:15310/13:33145709
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  • solvents; graphite; dispersions; bilayer graphene; molecular simulation; liquid-phase exfoliation (en)
http://linked.open.../riv/klicoveSlovo
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  • US - Spojené státy americké
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  • [A45CF99BCD2A]
http://linked.open...i/riv/nazevZdroje
  • Journal of Physical Chemistry Part C: Nanomaterials, Interfaces and Hard Matter
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  • 117
http://linked.open...iv/tvurceVysledku
  • Otyepka, Michal
  • Zbořil, Radek
  • Machalová Šišková, Karolína
  • Šafářová, Klára
  • Jurečka, Petr
  • Bourlinos, Athanasios B
  • Pykal, Martin
http://linked.open...ain/vavai/riv/wos
  • 000320214800042
issn
  • 1932-7447
number of pages
http://bibframe.org/vocab/doi
  • 10.1021/jp401277g
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  • 15310
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