About: The concept of compositional data analysis in practice - Total major element concentrations in agricultural and grazing land soils in Europe     Goto   Sponge   NotDistinct   Permalink

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Description
  • Applied geochemistry and environmental sciences invariably deal with compositional data. Classically, the original or log-transformed absolute element concentrations are studied. However, compositional data do not vary independently, and a concentration based approach to data analysis can lead to faulty conclusions. For this reason a better statistical approach was introduced in the 1980s, exclusively based on relative information. Because the difference between the two methods should be most pronounced in large-scale, and therefore highly variable, datasets, here a new dataset of agricultural soils, covering all of Europe (5.6 million km2) at an average sampling density of 1 site/2500 km2, is used to demonstrate and compare both approaches. Absolute element concentrations are certainly of interest in a variety of applications and can be provided in tabulations or concentration maps. Maps for the opened data (ratios to other elements) provide more specific additional information. For compositional data XY plots for raw or log-transformed data should only be used with care in an exploratory data analysis (EDA) sense, to detect unusual data behaviour, candidate subgroups of samples, or to compare pre-defined groups of samples. Correlation analysis and the Euclidean distance are not mathematically meaningful concepts for this data type. Element relationships have to be investigated via a stability measure of the (log-)ratios of elements. Logratios are also the key ingredient for an appropriate multivariate analysis of compositional data.
  • Applied geochemistry and environmental sciences invariably deal with compositional data. Classically, the original or log-transformed absolute element concentrations are studied. However, compositional data do not vary independently, and a concentration based approach to data analysis can lead to faulty conclusions. For this reason a better statistical approach was introduced in the 1980s, exclusively based on relative information. Because the difference between the two methods should be most pronounced in large-scale, and therefore highly variable, datasets, here a new dataset of agricultural soils, covering all of Europe (5.6 million km2) at an average sampling density of 1 site/2500 km2, is used to demonstrate and compare both approaches. Absolute element concentrations are certainly of interest in a variety of applications and can be provided in tabulations or concentration maps. Maps for the opened data (ratios to other elements) provide more specific additional information. For compositional data XY plots for raw or log-transformed data should only be used with care in an exploratory data analysis (EDA) sense, to detect unusual data behaviour, candidate subgroups of samples, or to compare pre-defined groups of samples. Correlation analysis and the Euclidean distance are not mathematically meaningful concepts for this data type. Element relationships have to be investigated via a stability measure of the (log-)ratios of elements. Logratios are also the key ingredient for an appropriate multivariate analysis of compositional data. (en)
Title
  • The concept of compositional data analysis in practice - Total major element concentrations in agricultural and grazing land soils in Europe
  • The concept of compositional data analysis in practice - Total major element concentrations in agricultural and grazing land soils in Europe (en)
skos:prefLabel
  • The concept of compositional data analysis in practice - Total major element concentrations in agricultural and grazing land soils in Europe
  • The concept of compositional data analysis in practice - Total major element concentrations in agricultural and grazing land soils in Europe (en)
skos:notation
  • RIV/61989592:15310/12:33141590!RIV13-MSM-15310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM6198959214)
http://linked.open...iv/cisloPeriodika
  • duben
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 128367
http://linked.open...ai/riv/idVysledku
  • RIV/61989592:15310/12:33141590
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Agricultural soil, XRF, Major elements, Europe, Geochemistry, Compositional data (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [DBEC5E9E4547]
http://linked.open...i/riv/nazevZdroje
  • Science of the Total Environment
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 426
http://linked.open...iv/tvurceVysledku
  • Hron, Karel
  • Filzmoser, Peter
  • Reimann, Clemens
  • Birke, Manfred
  • Demetriades, Alecos
  • Dinelli, Enrico
  • Fabian, Karl
  • Ladenberger, Anna
http://linked.open...ain/vavai/riv/wos
  • 000304795300023
http://linked.open...n/vavai/riv/zamer
issn
  • 0048-9697
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.scitotenv.2012.02.032
http://localhost/t...ganizacniJednotka
  • 15310
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