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  • Natural ferrihydrite was used as the precursors for the preparation of the nanocrystalline alpha-Fe powder using heat treatment in hydrogen atmosphere. Transformation temperatures were estimated from the temperature dependences of magnetic moment. Structure and phase composition of the precursors and the final powders were characterized by X-ray diffraction and Mössbauer spektroskopie. Magnetic properties were characterized according to hysteresis loop parameters. The kinetics of the transformation was described using Avrami relation applied on the data of the isothermal time dependence of magnetic moment measurements and subsequently the activation enthalpy of transformation was estimated using Arrhenius plots of their parameters. Comparison of the changes of activation enthalpies derived from a different temperature ranges indicates effects of different processes on formation of alpha-Fe nanoparticles.
  • Natural ferrihydrite was used as the precursors for the preparation of the nanocrystalline alpha-Fe powder using heat treatment in hydrogen atmosphere. Transformation temperatures were estimated from the temperature dependences of magnetic moment. Structure and phase composition of the precursors and the final powders were characterized by X-ray diffraction and Mössbauer spektroskopie. Magnetic properties were characterized according to hysteresis loop parameters. The kinetics of the transformation was described using Avrami relation applied on the data of the isothermal time dependence of magnetic moment measurements and subsequently the activation enthalpy of transformation was estimated using Arrhenius plots of their parameters. Comparison of the changes of activation enthalpies derived from a different temperature ranges indicates effects of different processes on formation of alpha-Fe nanoparticles. (en)
Title
  • Iron nanoparticles prepared from natural ferrihydrite precursor: kinetics and properties
  • Iron nanoparticles prepared from natural ferrihydrite precursor: kinetics and properties (en)
skos:prefLabel
  • Iron nanoparticles prepared from natural ferrihydrite precursor: kinetics and properties
  • Iron nanoparticles prepared from natural ferrihydrite precursor: kinetics and properties (en)
skos:notation
  • RIV/61989592:15310/11:33118136!RIV12-MSM-15310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(1M0512), P(GA106/08/1440)
http://linked.open...iv/cisloPeriodika
  • 11
http://linked.open...vai/riv/dodaniDat
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  • 205845
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  • RIV/61989592:15310/11:33118136
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  • Iron nanoparticles , Ferrihydrite , Reduction , Hydrogen, Magnetic moment, Activation enthalpy (en)
http://linked.open.../riv/klicoveSlovo
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  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [2BD3E219FAE5]
http://linked.open...i/riv/nazevZdroje
  • Journal of Nanoparticle Research
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  • 13
http://linked.open...iv/tvurceVysledku
  • David, Bohumil
  • Filip, Jan
  • Schneeweiss, Oldřich
  • Zbořil, Radek
  • Mašláň, Miroslav
http://linked.open...ain/vavai/riv/wos
  • 000297351600012
issn
  • 1388-0764
number of pages
http://bibframe.org/vocab/doi
  • 10.1007/s11051-011-0383-2
http://localhost/t...ganizacniJednotka
  • 15310
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