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  • Nanosized gama-Fe2O3 is one of the most remarkable iron(III) oxide polymorph with extensive applications in praktice. However, its exploitation in nanosized form is limited by presence of parasitic magnetic phenomena emerging if the size of gama-Fe2O3 nanoobjects falls below a certain threshold value. One of them is a spin canting negatively reflecting in a capability of these nanoobjects to be easily controlled by an external magnetic field. Knowledge of all parameters affecting spin canting may shed light into understanding of this parasitic phenomenon, thus enabling its prevention. For a study of spin canting, in-field 57Fe Mössbauer spectroscopy is widely recognized as the most powerful experimental tool allowing qualitative and quantitative determination of the degree of this phenomenon. In this work, we study the parameters having an impact on spin canting phenomenon occurring in the two gama-Fe2O3 nanoparticle systems exhibiting different average particle size and particle size distribution. It turns out that the spin canting phenomenon significantly depends on the temperature and its thermal evolution is influenced by average particle size and particle size distribution of a gama-Fe2O3 nanoparticle assembly. For smaller nanoparticles, diminishing of spin canting is assisted by collective magnetic excitations. Moreover, we propose a statistically-based procedure testing the nature and site-occurrence of spin canting phenomenon in the studied gama-Fe2O3 nanoparticle systems.
  • Nanosized gama-Fe2O3 is one of the most remarkable iron(III) oxide polymorph with extensive applications in praktice. However, its exploitation in nanosized form is limited by presence of parasitic magnetic phenomena emerging if the size of gama-Fe2O3 nanoobjects falls below a certain threshold value. One of them is a spin canting negatively reflecting in a capability of these nanoobjects to be easily controlled by an external magnetic field. Knowledge of all parameters affecting spin canting may shed light into understanding of this parasitic phenomenon, thus enabling its prevention. For a study of spin canting, in-field 57Fe Mössbauer spectroscopy is widely recognized as the most powerful experimental tool allowing qualitative and quantitative determination of the degree of this phenomenon. In this work, we study the parameters having an impact on spin canting phenomenon occurring in the two gama-Fe2O3 nanoparticle systems exhibiting different average particle size and particle size distribution. It turns out that the spin canting phenomenon significantly depends on the temperature and its thermal evolution is influenced by average particle size and particle size distribution of a gama-Fe2O3 nanoparticle assembly. For smaller nanoparticles, diminishing of spin canting is assisted by collective magnetic excitations. Moreover, we propose a statistically-based procedure testing the nature and site-occurrence of spin canting phenomenon in the studied gama-Fe2O3 nanoparticle systems. (en)
Title
  • SPIN CANTING OF gama-Fe2O3 NANOPARTICLES AND ITS EVALUATION EMPLOYING A STATISTICAL APPROACH
  • SPIN CANTING OF gama-Fe2O3 NANOPARTICLES AND ITS EVALUATION EMPLOYING A STATISTICAL APPROACH (en)
skos:prefLabel
  • SPIN CANTING OF gama-Fe2O3 NANOPARTICLES AND ITS EVALUATION EMPLOYING A STATISTICAL APPROACH
  • SPIN CANTING OF gama-Fe2O3 NANOPARTICLES AND ITS EVALUATION EMPLOYING A STATISTICAL APPROACH (en)
skos:notation
  • RIV/61989592:15310/11:33117956!RIV12-MSM-15310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(1M0512), P(ED2.1.00/03.0058), P(KAN115600801), Z(MSM6198959218)
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 231439
http://linked.open...ai/riv/idVysledku
  • RIV/61989592:15310/11:33117956
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Gamma-Fe2O3, maghemite, spin-canting, in-field 57Fe Mössbauer spectroscopy, regression models. . (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...ontrolniKodProRIV
  • [A5CF1C9396E7]
http://linked.open...v/mistoKonaniAkce
  • Brno, Czech Republic, EU
http://linked.open...i/riv/mistoVydani
  • Ostrava
http://linked.open...i/riv/nazevZdroje
  • NANOCON 2011 - Conference Proceedings, Different Authors
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...iv/tvurceVysledku
  • Tuček, Jiří
  • Tuček, Pavel
  • Tučková, Michaela
  • Šeděnková, Veronika
http://linked.open...vavai/riv/typAkce
http://linked.open.../riv/zahajeniAkce
http://linked.open...n/vavai/riv/zamer
number of pages
http://purl.org/ne...btex#hasPublisher
  • Tanger s.r.o.
https://schema.org/isbn
  • 978-80-87294-27-7
http://localhost/t...ganizacniJednotka
  • 15310
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