About: Tuning of the Critical Temperature in Iron(II) Spin-Crossover Materials Based on Bridging Polycyanidometallates: Pentacyanidonitrosylferrate(II) and Hexacyanidoplatinate(IV)

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Tuning of the Critical Temperature in Iron(II) Spin-Crossover Materials Based on Bridging Polycyanidometallates: Pentacyanidonitrosylferrate(II) and Hexacyanidoplatinate(IV) Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The reactions of iron(II) sulfate, 4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole (abpt), and pentacyanidonitrosylferrate(II) or hexacyanidoplatinate(IV) resulted in the formation of one-dimensional iron(II) spin-crossover compounds [Fe(abpt)2(u-Fe(CN)5(NO)]n (1) and [Fe(abpt)2(u-Pt(CN)6]n (2) with the spin-transition critical temperature near or above room temperature accompanied by thermochromism. Furthermore, it has been proven that the critical temperature Tc is influenced by the type of dianionic polycyanidometallate within the series of discussed systems, and it changes in the sequence of [Fe(CN)5(NO)](2-) { {Pt(CN)6](2-) { [Ni(CN)4](2-) approximate to [Pd(CN)4}(2-) approximate to [Pt(CN)4](2-). The reactions of iron(II) sulfate, 4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole (abpt), and pentacyanidonitrosylferrate(II) or hexacyanidoplatinate(IV) resulted in the formation of one-dimensional iron(II) spin-crossover compounds [Fe(abpt)2(u-Fe(CN)5(NO)]n (1) and [Fe(abpt)2(u-Pt(CN)6]n (2) with the spin-transition critical temperature near or above room temperature accompanied by thermochromism. Furthermore, it has been proven that the critical temperature Tc is influenced by the type of dianionic polycyanidometallate within the series of discussed systems, and it changes in the sequence of [Fe(CN)5(NO)](2-) { {Pt(CN)6](2-) { [Ni(CN)4](2-) approximate to [Pd(CN)4}(2-) approximate to [Pt(CN)4](2-). (en)
Title	Tuning of the Critical Temperature in Iron(II) Spin-Crossover Materials Based on Bridging Polycyanidometallates: Pentacyanidonitrosylferrate(II) and Hexacyanidoplatinate(IV) Tuning of the Critical Temperature in Iron(II) Spin-Crossover Materials Based on Bridging Polycyanidometallates: Pentacyanidonitrosylferrate(II) and Hexacyanidoplatinate(IV) (en)
skos:prefLabel	Tuning of the Critical Temperature in Iron(II) Spin-Crossover Materials Based on Bridging Polycyanidometallates: Pentacyanidonitrosylferrate(II) and Hexacyanidoplatinate(IV) Tuning of the Critical Temperature in Iron(II) Spin-Crossover Materials Based on Bridging Polycyanidometallates: Pentacyanidonitrosylferrate(II) and Hexacyanidoplatinate(IV) (en)
skos:notation	RIV/61989592:15310/11:33116857!RIV12-MSM-15310___
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(ED2.1.00/03.0058), P(EE2.3.20.0017), P(GAP207/11/0841), P(GP203/09/P370), P(KAN115600801)
http://linked.open...iv/cisloPeriodika	24
http://linked.open...vai/riv/dodaniDat	2012
http://linked.open...aciTvurceVysledku	Zbořil, Radek Trávníček, Zdeněk Herchel, Radovan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	236211
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/11:33116857
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Fe(II) complex, one-dimensional, spin crossover (en)
http://linked.open.../riv/klicoveSlovo	spin crossover Fe(II) complex one-dimensional
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[D15BEC1815AF]
http://linked.open...i/riv/nazevZdroje	Inorganic Chemistry
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Regional Centre of Advanced Technologies and Materials Functionalized Magnetic Carriers Based on Iron Oxide Nanoparticles with Bonded Biologically Active or Magnetically Interesting Compounds New technologies of preparation and exploitation of iron oxide-based nanoparticles for environmental, industrial and medical applications Research team development of the Regional Centre of Advanced Technologies and Materials Molecular magnetism based on transition metal complexes
http://linked.open...UplatneniVysledku	2011
http://linked.open...v/svazekPeriodika	50
http://linked.open...iv/tvurceVysledku	Herchel, Radovan Trávníček, Zdeněk Zbořil, Radek
issn	0020-1669
number of pages	3 (xsd:int)
http://bibframe.org/vocab/doi	10.1021/ic201702j
http://localhost/t...ganizacniJednotka	15310

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 48 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software