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  • Thermal decomposition of two garnets of near end-member composition ? almandine (Fe2.85Mg0.15)(Al1.99)Si2.99O12 and pyrope (Mg2.22Fe0.47Ca0.33)(Cr0.11Fe0.06Al1.81)Si2.98O12 ? has been carried out in reducing atmosphere (forming gas: 10% of H2 in N2). High-temperature behavior of both samples was monitored using simultaneous thermogravimetry and differential scanning calorimetry. The decomposition of almandine and pyrope turned out to proceed at slightly different temperatures above 1000 °C. Therefore, two series of samples were prepared based on the results of thermal analysis: almandine heated up to 950 °C, 1070 °C and 1200 °C, and pyrope heated up to 1000 °C, 1100 °C, 1125 °C and 1200 °C. The identification of the decomposition products was performed by X-ray powder diffraction and Mössbauer spectroscopy.
  • Thermal decomposition of two garnets of near end-member composition ? almandine (Fe2.85Mg0.15)(Al1.99)Si2.99O12 and pyrope (Mg2.22Fe0.47Ca0.33)(Cr0.11Fe0.06Al1.81)Si2.98O12 ? has been carried out in reducing atmosphere (forming gas: 10% of H2 in N2). High-temperature behavior of both samples was monitored using simultaneous thermogravimetry and differential scanning calorimetry. The decomposition of almandine and pyrope turned out to proceed at slightly different temperatures above 1000 °C. Therefore, two series of samples were prepared based on the results of thermal analysis: almandine heated up to 950 °C, 1070 °C and 1200 °C, and pyrope heated up to 1000 °C, 1100 °C, 1125 °C and 1200 °C. The identification of the decomposition products was performed by X-ray powder diffraction and Mössbauer spectroscopy. (en)
Title
  • High Temperature Decomposition of Almandine and Pyrope in Reducing Atmosphere
  • High Temperature Decomposition of Almandine and Pyrope in Reducing Atmosphere (en)
skos:prefLabel
  • High Temperature Decomposition of Almandine and Pyrope in Reducing Atmosphere
  • High Temperature Decomposition of Almandine and Pyrope in Reducing Atmosphere (en)
skos:notation
  • RIV/61989592:15310/10:10216347!RIV11-GA0-15310___
http://linked.open...avai/riv/aktivita
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  • P(1M0512), P(GA205/08/0869), P(KAN115600801), Z(MSM6198959218)
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  • 261535
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  • RIV/61989592:15310/10:10216347
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  • reducing atmosphere; thermal decomposition; Fe-bearing garnet (en)
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  • [5BC003667B42]
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  • Liptovský Ján, Slovensko
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  • Melville, New York
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  • AIP Conference Proceedings Series
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  • Filip, Jan
  • Mašláň, Miroslav
  • Aparicio Ordonez, Claudia J.S.
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issn
  • 0094-243X
number of pages
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  • American Institute of Physics
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  • 978-0-7354-0806-7
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  • 15310
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