About: X-ray structures and spectral characterization of simple ruthenium(II) nitrosyl complexes involving the [RuCl4(NO)(DMSO)]? or [RuCl4(NO)(H2O)]? complex anions

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: X-ray structures and spectral characterization of simple ruthenium(II) nitrosyl complexes involving the [RuCl4(NO)(DMSO)]? or [RuCl4(NO)(H2O)]? complex anions Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Three simple ruthenium nitrosyl complexes of the compositions [Et4N][RuCl4(NO)(DMSO](-) (1), [Bu4N][RuCl4(NO)(DMSO)](-) (2), and [Ph(4)P][RuCl4(NO)(H2O].DMSO (3); where DMSO = dimethyl sulfoxide, Et = ethyl, Bu = butyl and Ph = phenyl, have been synthesized in the single crystal form and their molecular and crystal structures have been determined. The Ru(II) centre is six-coordinated by four chlorido ligands in the equatorial plane and by the N (from NO+) and O (from DMSO in 1 and 2, H2O in 3) atoms in the axial positions forming an RuCI4NO donor set. The complexes have been also characterized by infrared and electronic spectroscopies, conductivity measurements, and thermogravimetric (TG) and differential thermal (DTA) analyses. The spectroscopic investigation is consistent with the (Ru(NO))(6) formulation with NO+ coordinated to the diamagnetic Ru(II) centre. The geometries of the complex anions as well as spectroscopic properties were calculated at the B3LYP/LANL2DZ/cc-pVTZ level of theory. Three simple ruthenium nitrosyl complexes of the compositions [Et4N][RuCl4(NO)(DMSO](-) (1), [Bu4N][RuCl4(NO)(DMSO)](-) (2), and [Ph(4)P][RuCl4(NO)(H2O].DMSO (3); where DMSO = dimethyl sulfoxide, Et = ethyl, Bu = butyl and Ph = phenyl, have been synthesized in the single crystal form and their molecular and crystal structures have been determined. The Ru(II) centre is six-coordinated by four chlorido ligands in the equatorial plane and by the N (from NO+) and O (from DMSO in 1 and 2, H2O in 3) atoms in the axial positions forming an RuCI4NO donor set. The complexes have been also characterized by infrared and electronic spectroscopies, conductivity measurements, and thermogravimetric (TG) and differential thermal (DTA) analyses. The spectroscopic investigation is consistent with the (Ru(NO))(6) formulation with NO+ coordinated to the diamagnetic Ru(II) centre. The geometries of the complex anions as well as spectroscopic properties were calculated at the B3LYP/LANL2DZ/cc-pVTZ level of theory. (en)
Title	X-ray structures and spectral characterization of simple ruthenium(II) nitrosyl complexes involving the [RuCl4(NO)(DMSO)]? or [RuCl4(NO)(H2O)]? complex anions X-ray structures and spectral characterization of simple ruthenium(II) nitrosyl complexes involving the [RuCl4(NO)(DMSO)]? or [RuCl4(NO)(H2O)]? complex anions (en)
skos:prefLabel	X-ray structures and spectral characterization of simple ruthenium(II) nitrosyl complexes involving the [RuCl4(NO)(DMSO)]? or [RuCl4(NO)(H2O)]? complex anions X-ray structures and spectral characterization of simple ruthenium(II) nitrosyl complexes involving the [RuCl4(NO)(DMSO)]? or [RuCl4(NO)(H2O)]? complex anions (en)
skos:notation	RIV/61989592:15310/10:10213203!RIV11-GA0-15310___
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GP203/08/P436), Z(MSM6198959218)
http://linked.open...iv/cisloPeriodika	1-3
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Trávníček, Zdeněk Novotná, Radka Matiková Mal'Arová, Miroslava
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	299063
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/10:10213203
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	DFT calculations; Thermal analysis; Infrared spectroscopy; Nitrosyl; Crystal structures; Ruthenium(II) complexes (en)
http://linked.open.../riv/klicoveSlovo	Thermal analysis Infrared spectroscopy DFT calculations Crystal structures Nitrosyl Ruthenium(II) complexes
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[3C71718B7752]
http://linked.open...i/riv/nazevZdroje	Journal of Molecular Structure
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Ru and Rh complexes with potential biological activity
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	977
http://linked.open...iv/tvurceVysledku	MATIKOVÁ MAĽAROVÁ, Miroslava NOVOTNÁ, Radka TRÁVNÍČEK, Zdeněk
http://linked.open...ain/vavai/riv/wos	000280498600028
http://linked.open...n/vavai/riv/zamer	Komplexní sloučeniny a oxidy přechodných kovů s využitím v bioaplikacích a nanotechnologiích
issn	0022-2860
number of pages	7 (xsd:int)
http://localhost/t...ganizacniJednotka	15310

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 48 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software