About: High-spin tetranuclear (Mn2Mn2IV)-Mn-II clusters with unique Mn(II)-Mn(IV) magnetic exchange: synthesis, structures and magnetism

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: High-spin tetranuclear (Mn2Mn2IV)-Mn-II clusters with unique Mn(II)-Mn(IV) magnetic exchange: synthesis, structures and magnetism Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Reactions of N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine (H(4)edte) with MnCl2 center dot 4H(2)O or FeCl3 center dot 6H(2)O in MeOH or MeCN with different bases yield four butterfly-like tetranuclear clusters with fused defective dicubane M4O6 cores: [(Mn2Mn2IV)-Mn-II(mu(4)-Hedte)(2)(thme)(2)]center dot MeCN (1) (H(4)edte = N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine, H(3)thme = 1,1,1-tris(hydroxymethyl)ethane), [(Mn2Mn2IV)-Mn-II(mu(4)-Hedte)(2)(thme)(2)]center dot 2MeOH (2), [Fe-4(III)(mu(4)-Hedte)(2)(N-3)(6)]center dot 2MeCN (3) and [Fe-4(III)(mu(4)-edte)(2)-(N-3)(4)(MeOH)(2)] (4). Both 1 and 3 crystallize in the triclinic space group P (1) over bar, while 2 and 4 crystallize in the monoclinic space group P2(1)/c and P2(1)/n, respectively. The hexadentate Hedte(3-) ligand in 1-3, and the edte(4-) ligand in 4 acts in a similar mu(4):eta(1):eta(1):eta(1):eta(2):eta(2):eta(3) coordination mode to bridge four metal ions into butterfly-like tetranuclear clusters with fused Reactions of N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine (H(4)edte) with MnCl2 center dot 4H(2)O or FeCl3 center dot 6H(2)O in MeOH or MeCN with different bases yield four butterfly-like tetranuclear clusters with fused defective dicubane M4O6 cores: [(Mn2Mn2IV)-Mn-II(mu(4)-Hedte)(2)(thme)(2)]center dot MeCN (1) (H(4)edte = N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine, H(3)thme = 1,1,1-tris(hydroxymethyl)ethane), [(Mn2Mn2IV)-Mn-II(mu(4)-Hedte)(2)(thme)(2)]center dot 2MeOH (2), [Fe-4(III)(mu(4)-Hedte)(2)(N-3)(6)]center dot 2MeCN (3) and [Fe-4(III)(mu(4)-edte)(2)-(N-3)(4)(MeOH)(2)] (4). Both 1 and 3 crystallize in the triclinic space group P (1) over bar, while 2 and 4 crystallize in the monoclinic space group P2(1)/c and P2(1)/n, respectively. The hexadentate Hedte(3-) ligand in 1-3, and the edte(4-) ligand in 4 acts in a similar mu(4):eta(1):eta(1):eta(1):eta(2):eta(2):eta(3) coordination mode to bridge four metal ions into butterfly-like tetranuclear clusters with fused (en)
Title	High-spin tetranuclear (Mn2Mn2IV)-Mn-II clusters with unique Mn(II)-Mn(IV) magnetic exchange: synthesis, structures and magnetism High-spin tetranuclear (Mn2Mn2IV)-Mn-II clusters with unique Mn(II)-Mn(IV) magnetic exchange: synthesis, structures and magnetism (en)
skos:prefLabel	High-spin tetranuclear (Mn2Mn2IV)-Mn-II clusters with unique Mn(II)-Mn(IV) magnetic exchange: synthesis, structures and magnetism High-spin tetranuclear (Mn2Mn2IV)-Mn-II clusters with unique Mn(II)-Mn(IV) magnetic exchange: synthesis, structures and magnetism (en)
skos:notation	RIV/61989592:15310/09:00010181!RIV10-MSM-15310___
http://linked.open...avai/riv/aktivita	Z
http://linked.open...avai/riv/aktivity	Z(MSM6198959218)
http://linked.open...iv/cisloPeriodika	17
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Herchel, Radovan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	317180
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/09:00010181
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	SINGLE-MOLECULE MAGNETS; WATER OXIDATION CENTER; CRYSTAL-STRUCTURES; CARBOXYLATE CLUSTERS; MANGANESE COMPLEXES; BUILDING-BLOCKS; HIGH-NUCLEARITY; GROUND-STATE; X-RAY; LIGANDS (en)
http://linked.open.../riv/klicoveSlovo	GROUND-STATE X-RAY BUILDING-BLOCKS MANGANESE COMPLEXES CRYSTAL-STRUCTURES LIGANDS CARBOXYLATE CLUSTERS HIGH-NUCLEARITY WATER OXIDATION CENTER SINGLE-MOLECULE MAGNETS
http://linked.open...odStatuVydavatele	GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV	[BF5CF4E39991]
http://linked.open...i/riv/nazevZdroje	Dalton Transactions
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	2009
http://linked.open...iv/tvurceVysledku	Herchel, Radovan Leng, Ji-Dong Tong, Ming-Liang Liu, Jun-Liang Zhou, Ai-Ju
http://linked.open...n/vavai/riv/zamer	Komplexní sloučeniny a oxidy přechodných kovů s využitím v bioaplikacích a nanotechnologiích
issn	1477-9226
number of pages	11 (xsd:int)
http://localhost/t...ganizacniJednotka	15310

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 77 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software