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  • A series of dinuclear Fe(III) complexes was synthesized in which the Schiff-base blocking ligand L-5 coordinates each of the centers which are linked by a bidentate, bipyridine-type ligand. For these systems, [(LFeIII)-Fe-5{bridge} (FeL5)-L-III](BPh4)(2), thermally induced spin crossover is observed. The corollary of the systems is that the spin crossover interferes with the magnetic exchange interaction. The overlap of the energy bands of the LL and HH reference states (L, low-spin; H, high-spin) causes the exchange interaction to act against the spin crossover (leading to incompleteness or gradual behavior).
  • A series of dinuclear Fe(III) complexes was synthesized in which the Schiff-base blocking ligand L-5 coordinates each of the centers which are linked by a bidentate, bipyridine-type ligand. For these systems, [(LFeIII)-Fe-5{bridge} (FeL5)-L-III](BPh4)(2), thermally induced spin crossover is observed. The corollary of the systems is that the spin crossover interferes with the magnetic exchange interaction. The overlap of the energy bands of the LL and HH reference states (L, low-spin; H, high-spin) causes the exchange interaction to act against the spin crossover (leading to incompleteness or gradual behavior). (en)
Title
  • Dinuclear Fe(III) complexes with spin crossover
  • Dinuclear Fe(III) complexes with spin crossover (en)
skos:prefLabel
  • Dinuclear Fe(III) complexes with spin crossover
  • Dinuclear Fe(III) complexes with spin crossover (en)
skos:notation
  • RIV/61989592:15310/09:00010180!RIV10-MSM-15310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(KAN115600801), Z(MSM6198959218)
http://linked.open...iv/cisloPeriodika
  • 7
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 310623
http://linked.open...ai/riv/idVysledku
  • RIV/61989592:15310/09:00010180
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Spin crossover; Exchange interaction; Dinuclear iron(III) complexes; Schiff-base ligands (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [52829F531576]
http://linked.open...i/riv/nazevZdroje
  • Monatshefte für Chemie
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 140
http://linked.open...iv/tvurceVysledku
  • Herchel, Radovan
  • Trávníček, Zdeněk
  • Boča, Roman
  • Nemec, Ivan
  • Linert, Wolfgang
  • Gembický, Milan
http://linked.open...n/vavai/riv/zamer
issn
  • 0026-9247
number of pages
http://localhost/t...ganizacniJednotka
  • 15310
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