About: Coordination Chemistry of Conformation-Flexible 1,2,3,4,5,6-Cyclohexanehexacarboxylate: Trapping Various Conformations in Metal-Organic Frameworks

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About: Coordination Chemistry of Conformation-Flexible 1,2,3,4,5,6-Cyclohexanehexacarboxylate: Trapping Various Conformations in Metal-Organic Frameworks Goto Sponge NotDistinct Permalink

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Description	To study the conformations of 1,2,3,4,5,6-cyclohexanehexacarboxylic acid (H6L), eleven new coordination polymers have been isolated from hydrothermal reactions of different metal salts with 1e,2a,3e,4a,5e,6a-cyclohexanehexacarboxylic acid (3e+3a, H6LI) and characterized. They are [Cd12(6-LII)(10-LII)3(-H2O)6(H2O)6]16.5 H2O (1), Na12[Cd6(6-LII)(6-LIII)3]27 H2O (2), [Cd3(13-LII)(-H2O)] (3), [Cd3(6-LIII)(2,2-bpy)3(H2O)3]2 H2O (4), [Cd4(4-LVI)2(4,4-Hbpy)4(4,4-bpy)2(H2O)4]9.5 H2O (5), [Cd2(6-LII)(4,4-Hbpy)2(H2O)10]5 H2O (6), [Cd3(11-LVI)(H2O)3] (7), [M3(9-LII)(H2O)6] (M=Mn (8), Fe (9), and Ni (10)), and [Ni4(OH)2(10-LII)(4,4-bpy)(H2O)4]6 H2O (11). Three new conformations of 1,2,3,4,5,6-cyclohexanehexacarboxylate, 6e (LII), 4e+2a (LIII) and 5e+1a (LVI), have been derived from the conformational conversions of LI and trapped in these complexes by controlling the conditions of the hydrothermal systems. Complexes 1 and 2 have three-dimensional (3D) coordination frameworks with nanoscale cages and are obtained To study the conformations of 1,2,3,4,5,6-cyclohexanehexacarboxylic acid (H6L), eleven new coordination polymers have been isolated from hydrothermal reactions of different metal salts with 1e,2a,3e,4a,5e,6a-cyclohexanehexacarboxylic acid (3e+3a, H6LI) and characterized. They are [Cd12(6-LII)(10-LII)3(-H2O)6(H2O)6]16.5 H2O (1), Na12[Cd6(6-LII)(6-LIII)3]27 H2O (2), [Cd3(13-LII)(-H2O)] (3), [Cd3(6-LIII)(2,2-bpy)3(H2O)3]2 H2O (4), [Cd4(4-LVI)2(4,4-Hbpy)4(4,4-bpy)2(H2O)4]9.5 H2O (5), [Cd2(6-LII)(4,4-Hbpy)2(H2O)10]5 H2O (6), [Cd3(11-LVI)(H2O)3] (7), [M3(9-LII)(H2O)6] (M=Mn (8), Fe (9), and Ni (10)), and [Ni4(OH)2(10-LII)(4,4-bpy)(H2O)4]6 H2O (11). Three new conformations of 1,2,3,4,5,6-cyclohexanehexacarboxylate, 6e (LII), 4e+2a (LIII) and 5e+1a (LVI), have been derived from the conformational conversions of LI and trapped in these complexes by controlling the conditions of the hydrothermal systems. Complexes 1 and 2 have three-dimensional (3D) coordination frameworks with nanoscale cages and are obtained (en)
Title	Coordination Chemistry of Conformation-Flexible 1,2,3,4,5,6-Cyclohexanehexacarboxylate: Trapping Various Conformations in Metal-Organic Frameworks Coordination Chemistry of Conformation-Flexible 1,2,3,4,5,6-Cyclohexanehexacarboxylate: Trapping Various Conformations in Metal-Organic Frameworks (en)
skos:prefLabel	Coordination Chemistry of Conformation-Flexible 1,2,3,4,5,6-Cyclohexanehexacarboxylate: Trapping Various Conformations in Metal-Organic Frameworks Coordination Chemistry of Conformation-Flexible 1,2,3,4,5,6-Cyclohexanehexacarboxylate: Trapping Various Conformations in Metal-Organic Frameworks (en)
skos:notation	RIV/61989592:15310/08:00009951!RIV10-MSM-15310___
http://linked.open...avai/riv/aktivita	S Z
http://linked.open...avai/riv/aktivity	S, Z(MSM6198959218)
http://linked.open...iv/cisloPeriodika	24
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Herchel, Radovan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	361329
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/08:00009951
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	conformation analysis; coordination polymers; cyclohexanehexacarboxylate; hydrothermal synthesis; magnetic properties (en)
http://linked.open.../riv/klicoveSlovo	conformation analysis coordination polymers hydrothermal synthesis magnetic properties cyclohexanehexacarboxylate
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[4378EE00048C]
http://linked.open...i/riv/nazevZdroje	Chemistry - A European Journal
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	14
http://linked.open...iv/tvurceVysledku	Herchel, Radovan Tong, Ming-Liang Wang, Jing Lin, Zhuo-Jia Ou, Yong-Cong Shen, Yong
http://linked.open...n/vavai/riv/zamer	Komplexní sloučeniny a oxidy přechodných kovů s využitím v bioaplikacích a nanotechnologiích
issn	0947-6539
number of pages	18 (xsd:int)
http://localhost/t...ganizacniJednotka	15310

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