About: ([mu]-5-Carboxybenzene-1,3-dicarboxylato-[kappa]2O1:O3)bis[bis(2,2'-bipyridine-[kappa]2N,N')copper(II)] 5-carboxybenzene-1,3-dicarboxylate 2,2'-bipyridine solvate tridecahydrate     Goto   Sponge   NotDistinct   Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

AttributesValues
rdf:type
Description
  • The asymmetric unit of the title complex, [Cu2(C9H4O6)(C10H8N2)4](C9H4O6).C10H8N2.13H2O, comprises two formula units. The two CuII centres are bridged by a 5-carboxybenzene-1,3-dicarboxylate (Hbtc) ligand. Each of the metal centres is bonded to four N atoms of two bidentate 2,2'-bipyridine ligands (bpy) and one O atom of the Hbtc ligand in a highly distorted square-pyramidal geometry. The secondary structure is stabilized by a variety of O-H...O hydrogen bonds and [pi]-[pi] stacking interactions connecting the complex cations, Hbtc anions, bpy and water molecules of crystallization. Three water molecules are disordered over two positions, with site occupancy factors of ca 0.8 and 0.2.
  • The asymmetric unit of the title complex, [Cu2(C9H4O6)(C10H8N2)4](C9H4O6).C10H8N2.13H2O, comprises two formula units. The two CuII centres are bridged by a 5-carboxybenzene-1,3-dicarboxylate (Hbtc) ligand. Each of the metal centres is bonded to four N atoms of two bidentate 2,2'-bipyridine ligands (bpy) and one O atom of the Hbtc ligand in a highly distorted square-pyramidal geometry. The secondary structure is stabilized by a variety of O-H...O hydrogen bonds and [pi]-[pi] stacking interactions connecting the complex cations, Hbtc anions, bpy and water molecules of crystallization. Three water molecules are disordered over two positions, with site occupancy factors of ca 0.8 and 0.2. (en)
  • Byla vyřešena molekulová struktura komplexu o složení [Cu2(C9H4O6)(C10H8N2)4](C9H4O6).C10H8N2.13H2O, kde atomy mědi jsou spojeny 5-karboxybenzen-1,3-dikarboxylato (Hbtc) můstkovým ligandem. Navíc je každý atom mědi koordinován dvěma 2,2'-bipyridin ligandy. (cs)
Title
  • ([mu]-5-Carboxybenzene-1,3-dicarboxylato-[kappa]2O1:O3)bis[bis(2,2'-bipyridine-[kappa]2N,N')copper(II)] 5-carboxybenzene-1,3-dicarboxylate 2,2'-bipyridine solvate tridecahydrate
  • ([mu]-5-Carboxybenzene-1,3-dicarboxylato-[kappa]2O1:O3)bis[bis(2,2'-bipyridine-[kappa]2N,N')copper(II)] 5-carboxybenzene-1,3-dicarboxylate 2,2'-bipyridine solvate tridecahydrate (en)
  • ([mu]-5-Karboxybenzen-1,3-dikarboxylato-[kappa]2O1:O3)bis[bis(2,2'-bipyridin-[kappa]2N,N')měď(II)] 5-karboxybenzen-1,3-dikarboxylate 2,2'-bipyridin solvát tridekahydrát (cs)
skos:prefLabel
  • ([mu]-5-Carboxybenzene-1,3-dicarboxylato-[kappa]2O1:O3)bis[bis(2,2'-bipyridine-[kappa]2N,N')copper(II)] 5-carboxybenzene-1,3-dicarboxylate 2,2'-bipyridine solvate tridecahydrate
  • ([mu]-5-Carboxybenzene-1,3-dicarboxylato-[kappa]2O1:O3)bis[bis(2,2'-bipyridine-[kappa]2N,N')copper(II)] 5-carboxybenzene-1,3-dicarboxylate 2,2'-bipyridine solvate tridecahydrate (en)
  • ([mu]-5-Karboxybenzen-1,3-dikarboxylato-[kappa]2O1:O3)bis[bis(2,2'-bipyridin-[kappa]2N,N')měď(II)] 5-karboxybenzen-1,3-dikarboxylate 2,2'-bipyridin solvát tridekahydrát (cs)
skos:notation
  • RIV/61989592:15310/08:00005559!RIV09-MSM-15310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM6198959218)
http://linked.open...iv/cisloPeriodika
  • 2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 381317
http://linked.open...ai/riv/idVysledku
  • RIV/61989592:15310/08:00005559
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • single-crystal X-ray study; T = 120 K; mean sigma(C-C) = 0.005 A°; H-atom completeness 96%; disorder in solvent or counterion; R factor = 0.035; wR factor = 0.086; data-to-parameter ratio = 11.5. (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DK - Dánské království
http://linked.open...ontrolniKodProRIV
  • [94D3E2E0772D]
http://linked.open...i/riv/nazevZdroje
  • Acta Crystallographica Section E - Structure Reports Online
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 64
http://linked.open...iv/tvurceVysledku
  • Marek, Jaromír
  • Trávníček, Zdeněk
http://linked.open...n/vavai/riv/zamer
issn
  • 1600-5368
number of pages
http://localhost/t...ganizacniJednotka
  • 15310
Faceted Search & Find service v1.16.118 as of Jun 21 2024


Alternative Linked Data Documents: ODE     Content Formats:   [cxml] [csv]     RDF   [text] [turtle] [ld+json] [rdf+json] [rdf+xml]     ODATA   [atom+xml] [odata+json]     Microdata   [microdata+json] [html]    About   
This material is Open Knowledge   W3C Semantic Web Technology [RDF Data] Valid XHTML + RDFa
OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 48 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software