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Description
| - The asymmetric unit of the title complex, [Cu2(C9H4O6)(C10H8N2)4](C9H4O6).C10H8N2.13H2O, comprises two formula units. The two CuII centres are bridged by a 5-carboxybenzene-1,3-dicarboxylate (Hbtc) ligand. Each of the metal centres is bonded to four N atoms of two bidentate 2,2'-bipyridine ligands (bpy) and one O atom of the Hbtc ligand in a highly distorted square-pyramidal geometry. The secondary structure is stabilized by a variety of O-H...O hydrogen bonds and [pi]-[pi] stacking interactions connecting the complex cations, Hbtc anions, bpy and water molecules of crystallization. Three water molecules are disordered over two positions, with site occupancy factors of ca 0.8 and 0.2.
- The asymmetric unit of the title complex, [Cu2(C9H4O6)(C10H8N2)4](C9H4O6).C10H8N2.13H2O, comprises two formula units. The two CuII centres are bridged by a 5-carboxybenzene-1,3-dicarboxylate (Hbtc) ligand. Each of the metal centres is bonded to four N atoms of two bidentate 2,2'-bipyridine ligands (bpy) and one O atom of the Hbtc ligand in a highly distorted square-pyramidal geometry. The secondary structure is stabilized by a variety of O-H...O hydrogen bonds and [pi]-[pi] stacking interactions connecting the complex cations, Hbtc anions, bpy and water molecules of crystallization. Three water molecules are disordered over two positions, with site occupancy factors of ca 0.8 and 0.2. (en)
- Byla vyřešena molekulová struktura komplexu o složení [Cu2(C9H4O6)(C10H8N2)4](C9H4O6).C10H8N2.13H2O, kde atomy mědi jsou spojeny 5-karboxybenzen-1,3-dikarboxylato (Hbtc) můstkovým ligandem. Navíc je každý atom mědi koordinován dvěma 2,2'-bipyridin ligandy. (cs)
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Title
| - ([mu]-5-Carboxybenzene-1,3-dicarboxylato-[kappa]2O1:O3)bis[bis(2,2'-bipyridine-[kappa]2N,N')copper(II)] 5-carboxybenzene-1,3-dicarboxylate 2,2'-bipyridine solvate tridecahydrate
- ([mu]-5-Carboxybenzene-1,3-dicarboxylato-[kappa]2O1:O3)bis[bis(2,2'-bipyridine-[kappa]2N,N')copper(II)] 5-carboxybenzene-1,3-dicarboxylate 2,2'-bipyridine solvate tridecahydrate (en)
- ([mu]-5-Karboxybenzen-1,3-dikarboxylato-[kappa]2O1:O3)bis[bis(2,2'-bipyridin-[kappa]2N,N')měď(II)] 5-karboxybenzen-1,3-dikarboxylate 2,2'-bipyridin solvát tridekahydrát (cs)
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skos:prefLabel
| - ([mu]-5-Carboxybenzene-1,3-dicarboxylato-[kappa]2O1:O3)bis[bis(2,2'-bipyridine-[kappa]2N,N')copper(II)] 5-carboxybenzene-1,3-dicarboxylate 2,2'-bipyridine solvate tridecahydrate
- ([mu]-5-Carboxybenzene-1,3-dicarboxylato-[kappa]2O1:O3)bis[bis(2,2'-bipyridine-[kappa]2N,N')copper(II)] 5-carboxybenzene-1,3-dicarboxylate 2,2'-bipyridine solvate tridecahydrate (en)
- ([mu]-5-Karboxybenzen-1,3-dikarboxylato-[kappa]2O1:O3)bis[bis(2,2'-bipyridin-[kappa]2N,N')měď(II)] 5-karboxybenzen-1,3-dikarboxylate 2,2'-bipyridin solvát tridekahydrát (cs)
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skos:notation
| - RIV/61989592:15310/08:00005559!RIV09-MSM-15310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61989592:15310/08:00005559
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - single-crystal X-ray study; T = 120 K; mean sigma(C-C) = 0.005 A°; H-atom completeness 96%; disorder in solvent or counterion; R factor = 0.035; wR factor = 0.086; data-to-parameter ratio = 11.5. (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Acta Crystallographica Section E - Structure Reports Online
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Marek, Jaromír
- Trávníček, Zdeněk
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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