About: 6-(2-chlorobenzylamino)purinium tetra-chlorido(dimethyl sulfoxide-kappa O)(nitrosyl-kappa N)ruthenate(III) monohydrate     Goto   Sponge   NotDistinct   Permalink

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Description
  • Byla studována struktura komplexní soli monohydrátu tetrarachloro-(dimethylsulfoxido-kappa O)(nitrosyl-kappa N)ruthenitanu 6-(2-chlorbenzylamino)purinia pomocí rentgenostrukturní analýzy. (cs)
  • The asymmetric unit of the title complex salt, (C12H11ClN5)-[RuCl4(NO)(C2H6OS)]center dot H2O, contains a 6-(2-chlorobenzyl-amino) purinium cation, a tetrachlorido(dimethylsulfoxide)nitrosylruthenate(III) anion and one solvent water molecule. The Ru-III atom is octahedrally coordinated by four Cl atoms in the equatorial plane, and by a dimethyl sulfoxide O atom and a nitrosyl N atom in axial positions. The cation is an N3-protonated N7 tautomer. Intermolecular N-H center dot center dot center dot N hydrogen bonds connect two cations into centrosymmetric dimers, with an N center dot center dot center dot N distance of 2.821 (4) A. The crystal structure also involves N-H center dot center dot center dot O, N-H center dot center dot center dot Cl and O-H center dot center dot center dot Cl hydrogen bonds.
  • The asymmetric unit of the title complex salt, (C12H11ClN5)-[RuCl4(NO)(C2H6OS)]center dot H2O, contains a 6-(2-chlorobenzyl-amino) purinium cation, a tetrachlorido(dimethylsulfoxide)nitrosylruthenate(III) anion and one solvent water molecule. The Ru-III atom is octahedrally coordinated by four Cl atoms in the equatorial plane, and by a dimethyl sulfoxide O atom and a nitrosyl N atom in axial positions. The cation is an N3-protonated N7 tautomer. Intermolecular N-H center dot center dot center dot N hydrogen bonds connect two cations into centrosymmetric dimers, with an N center dot center dot center dot N distance of 2.821 (4) A. The crystal structure also involves N-H center dot center dot center dot O, N-H center dot center dot center dot Cl and O-H center dot center dot center dot Cl hydrogen bonds. (en)
Title
  • 6-(2-chlorobenzylamino)purinium tetra-chlorido(dimethyl sulfoxide-kappa O)(nitrosyl-kappa N)ruthenate(III) monohydrate
  • 6-(2-chlorobenzylamino)purinium tetra-chlorido(dimethyl sulfoxide-kappa O)(nitrosyl-kappa N)ruthenate(III) monohydrate (en)
  • Tetrachloro-(dimethylsulfoxido-kappa O)(nitrosyl-kappa N)ruthenitan 6-(2-chlorbenzylamino)purinia monohydrát (cs)
skos:prefLabel
  • 6-(2-chlorobenzylamino)purinium tetra-chlorido(dimethyl sulfoxide-kappa O)(nitrosyl-kappa N)ruthenate(III) monohydrate
  • 6-(2-chlorobenzylamino)purinium tetra-chlorido(dimethyl sulfoxide-kappa O)(nitrosyl-kappa N)ruthenate(III) monohydrate (en)
  • Tetrachloro-(dimethylsulfoxido-kappa O)(nitrosyl-kappa N)ruthenitan 6-(2-chlorbenzylamino)purinia monohydrát (cs)
skos:notation
  • RIV/61989592:15310/08:00005485!RIV09-MSM-15310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM6198959218)
http://linked.open...iv/cisloPeriodika
  • 4
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 407737
http://linked.open...ai/riv/idVysledku
  • RIV/61989592:15310/08:00005485
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • X-RAY-STRUCTURE; CHLORIDE; COMPLEXES; DERIVATIVES (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DK - Dánské království
http://linked.open...ontrolniKodProRIV
  • [2476A1545201]
http://linked.open...i/riv/nazevZdroje
  • Acta Crystallographica Section E - Structure Reports Online
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 64
http://linked.open...iv/tvurceVysledku
  • Trávníček, Zdeněk
  • Štěpánková, Kamila
  • Matiková Mal'arová, Miroslava
http://linked.open...n/vavai/riv/zamer
issn
  • 1600-5368
number of pages
http://localhost/t...ganizacniJednotka
  • 15310
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