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| Description
| - Bylo provedeno srovnání strukturních, spektroskopických, elektrochemických a magnetických vlastností pyrazolátových a karboxylátových komplexů [Fe-3(mu(3)(mu O-3)(mu-LL)(6)Cl-3](2-), teré obsahují motiv Fe-3(mu(3)-O). Zatímco Fe-3(mu(3)-O)-uspořádání jsou strukturně nerozlišitelná u obou typů komplexů, jejich magnetické vlastnosti se liší z důvodu příspěvku pyrazolu k celkové antiferromagnetické interakci: J(1)/hc -80.1 cm(-1) a J(2)/hc = -72.4 cm(-1) nebo J(1)/hc = 70.6 cm(-1) and J(2)/hc = -80.8 cm(-1), (H-ex = -J(1)(S1S2 + S2S3) J(2)S(1)S(3)). Magnetické vlastnosti komplexů s pyrazolem jsou také odlišné z důvodu antisymetrické výměnné interakce. (cs)
- A comparison is made between the structural, spectroscopic, electrochemical, and magnetic properties of pyrazolate versus carboxylate complexes [Fe-3(mu(3)(mu O-3)(mu-LL)(6)Cl-3](2-) containing the Fe-3(mu(3)-O)-motif. While the Fe-3(mu(3)-O)-cores are structurally indistinguishable in the two types of complexes, their magnetic properties deviate from the expected values as a result of a through-pyrazole contribution to the overall antiferromagnetic exchange with J(1)/hc -80.1 cm(-1) and J(2)/hc = -72.4 cm(-1), or J(1)/hc = 70.6 cm(-1) and J(2)/hc = -80.8 cm(-1), (H-ex = -J(1)(S1S2 + S2S3) J(2)S(1)S(3)). The magnetic properties of the pyrazolate complexes are further tuned by an antisymmetric exchange interaction term.
- A comparison is made between the structural, spectroscopic, electrochemical, and magnetic properties of pyrazolate versus carboxylate complexes [Fe-3(mu(3)(mu O-3)(mu-LL)(6)Cl-3](2-) containing the Fe-3(mu(3)-O)-motif. While the Fe-3(mu(3)-O)-cores are structurally indistinguishable in the two types of complexes, their magnetic properties deviate from the expected values as a result of a through-pyrazole contribution to the overall antiferromagnetic exchange with J(1)/hc -80.1 cm(-1) and J(2)/hc = -72.4 cm(-1), or J(1)/hc = 70.6 cm(-1) and J(2)/hc = -80.8 cm(-1), (H-ex = -J(1)(S1S2 + S2S3) J(2)S(1)S(3)). The magnetic properties of the pyrazolate complexes are further tuned by an antisymmetric exchange interaction term. (en)
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| Title
| - A pyrazolate-supported Fe-3(mu(3)-O) core: Structural, spectroscopic, electrochemical, and magnetic study
- Strukturní motiv Fe-3(mu(3)-O) doplněný pyrazolem: Strukturní, spektroskopické, elektrochemické a magnetické studium (cs)
- A pyrazolate-supported Fe-3(mu(3)-O) core: Structural, spectroscopic, electrochemical, and magnetic study (en)
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| skos:prefLabel
| - A pyrazolate-supported Fe-3(mu(3)-O) core: Structural, spectroscopic, electrochemical, and magnetic study
- Strukturní motiv Fe-3(mu(3)-O) doplněný pyrazolem: Strukturní, spektroskopické, elektrochemické a magnetické studium (cs)
- A pyrazolate-supported Fe-3(mu(3)-O) core: Structural, spectroscopic, electrochemical, and magnetic study (en)
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| skos:notation
| - RIV/61989592:15310/07:00004830!RIV08-MSM-15310___
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| http://linked.open.../vavai/riv/strany
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
| |
| http://linked.open...ai/riv/idVysledku
| - RIV/61989592:15310/07:00004830
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| http://linked.open...riv/jazykVysledku
| |
| http://linked.open.../riv/klicovaSlova
| - SINGLE-MOLECULE MAGNETS; ELECTRON-PARAMAGNETIC-RES; MIXED-VALENCE COMPLEXES; ANTISYMMETRIC EXCHANGE; CRYSTAL-STRUCTURE; CARBOXYLATE CHEMISTRY; IRON(III) CARBOXYLATE; VIBRATIONAL-SPECTRA; WEAK FERROMAGNETISM; TRINUCLEAR CLUSTER (en)
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| http://linked.open.../riv/klicoveSlovo
| |
| http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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| http://linked.open...ontrolniKodProRIV
| |
| http://linked.open...i/riv/nazevZdroje
| |
| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...UplatneniVysledku
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| http://linked.open...v/svazekPeriodika
| |
| http://linked.open...iv/tvurceVysledku
| - Herchel, Radovan
- Boča, Roman
- Raptis, Raphael G.
- Sanakis, Yiannis
- Renz, Franz
- Baran, Peter
- Pinero, Dalice
- Klein, Michael
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| http://linked.open...n/vavai/riv/zamer
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| issn
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| number of pages
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| http://localhost/t...ganizacniJednotka
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