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  • The syntheses of amorphous Fe2O3 nanoparticles of varying size and morphology, their magnetic properties, crystallization mechanism, and applications are reviewed herein. The synthetic routes are classified according to the nature of the sample (powders, nanocomposites, films, coated particles). The contributions of various experimental techniques to the characterization of an amorphous Fe2O3 phase are considered in this review, including some key experimental markers, allowing its distinction from nanocrystalline %22X-ray amorphous%22 polymorphs (maghemite, hematite). We discuss the thermally induced crystallization mechanisms depending on transformation temperature, atmosphere, and the size of the amorphous particles that predetermine the structure of the primarily formed crystalline polymorph. The controversial description of the magnetic behavior, including an interpretation of the low-temperature and in-field Mossbauer spectra, is analyzed.
  • The syntheses of amorphous Fe2O3 nanoparticles of varying size and morphology, their magnetic properties, crystallization mechanism, and applications are reviewed herein. The synthetic routes are classified according to the nature of the sample (powders, nanocomposites, films, coated particles). The contributions of various experimental techniques to the characterization of an amorphous Fe2O3 phase are considered in this review, including some key experimental markers, allowing its distinction from nanocrystalline %22X-ray amorphous%22 polymorphs (maghemite, hematite). We discuss the thermally induced crystallization mechanisms depending on transformation temperature, atmosphere, and the size of the amorphous particles that predetermine the structure of the primarily formed crystalline polymorph. The controversial description of the magnetic behavior, including an interpretation of the low-temperature and in-field Mossbauer spectra, is analyzed. (en)
Title
  • Amorphous Iron(III) Oxide - A Review
  • Amorphous Iron(III) Oxide - A Review (en)
skos:prefLabel
  • Amorphous Iron(III) Oxide - A Review
  • Amorphous Iron(III) Oxide - A Review (en)
skos:notation
  • RIV/61989592:15310/07:00003551!RIV10-MSM-15310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(1H-PK/44), P(1M0512), Z(MSM6198959218)
http://linked.open...iv/cisloPeriodika
  • 16
http://linked.open...vai/riv/dodaniDat
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  • 409242
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  • RIV/61989592:15310/07:00003551
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  • Amorphous Iron(III) Oxide (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [D1F63E18EA0D]
http://linked.open...i/riv/nazevZdroje
  • Journal of Physical Chemistry B
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 111
http://linked.open...iv/tvurceVysledku
  • Zbořil, Radek
  • Machala, Libor
  • Gedanken, Aharon
http://linked.open...n/vavai/riv/zamer
issn
  • 1520-6106
number of pages
http://localhost/t...ganizacniJednotka
  • 15310
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