About: Tetracyanopalladnates(II) and tetracyanoplatinates(II) of copper(II) with triamines or tetramines as chelating ligands

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About: Tetracyanopalladnates(II) and tetracyanoplatinates(II) of copper(II) with triamines or tetramines as chelating ligands Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Osm nových komplexů o složení [Cu(L)Pd(CN)4].xH2O a [Cu(L)Pt(CN)4] (L = 1,4-bis(3-aminopropyl)piperazin); N,N´-bis(3-aminopropyl)-1,2-diaminoethan, dipropylentriamin, N-(2-aminoethyl)-1,3-diaminopropan) byly připraveny reakcí K2[M(CN)4] (M=Pd, Pt) s komplexem [Cu(L)](ClO4)2 nebo Cu(ClO4)2.6H2O a vhodným aminem ve vodě a charakterizovány pomocí IR spekter a magnetického měření. Teplotní závislost magnetické susceptibility byla změřena u komplexu [Cu(L)Pd(CN)4].H2O (L = N,N´-bis(3-aminopropyl)-1,2-diaminoethan) ale výměnná interakce mezi atomy mědi(II) nebyla nalezena. (cs) Eight new complexes of composition [Cu(L)Pd(CN)4].xH2O and [Cu(L)Pt(CN)4] (L = 1,4-bis(3-aminopropyl)piperazine); N,N´-bis(3-aminopropyl)-1,2-diaminoethane, dipropylenetriamine, N-(2-aminoethyl)-1,3-diaminopropane) have been prepared by the reactions of K2[M(CN)4] (M=Pd, Pt) with the complex [Cu(L)](ClO4)2 or Cu(ClO4)2.6H2O and appropriate amine in water and characterized by IR and magnetic measurements. The temperature dependence of magnetic susceptibility was measured for complex [Cu(L)Pd(CN)4].H2O (L = N,N´-bis(3-aminopropyl)-1,2-diaminoethane) but exchange interaction between copper(II) atoms was not found. Eight new complexes of composition [Cu(L)Pd(CN)4].xH2O and [Cu(L)Pt(CN)4] (L = 1,4-bis(3-aminopropyl)piperazine); N,N´-bis(3-aminopropyl)-1,2-diaminoethane, dipropylenetriamine, N-(2-aminoethyl)-1,3-diaminopropane) have been prepared by the reactions of K2[M(CN)4] (M=Pd, Pt) with the complex [Cu(L)](ClO4)2 or Cu(ClO4)2.6H2O and appropriate amine in water and characterized by IR and magnetic measurements. The temperature dependence of magnetic susceptibility was measured for complex [Cu(L)Pd(CN)4].H2O (L = N,N´-bis(3-aminopropyl)-1,2-diaminoethane) but exchange interaction between copper(II) atoms was not found. (en)
Title	Tetracyanopalladnates(II) and tetracyanoplatinates(II) of copper(II) with triamines or tetramines as chelating ligands Tetracyanopalladnates(II) and tetracyanoplatinates(II) of copper(II) with triamines or tetramines as chelating ligands (en) Tetrakyanopalladnatany a tetrakyanoplatnatany měďnaté s triaminy a tetraminy jako chelatotvornými ligandy (cs)
skos:prefLabel	Tetracyanopalladnates(II) and tetracyanoplatinates(II) of copper(II) with triamines or tetramines as chelating ligands Tetracyanopalladnates(II) and tetracyanoplatinates(II) of copper(II) with triamines or tetramines as chelating ligands (en) Tetrakyanopalladnatany a tetrakyanoplatnatany měďnaté s triaminy a tetraminy jako chelatotvornými ligandy (cs)
skos:notation	RIV/61989592:15310/06:00002648!RIV07-GA0-15310___
http://linked.open.../vavai/riv/strany	43-51
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(GA203/98/P221)
http://linked.open...iv/cisloPeriodika	-
http://linked.open...vai/riv/dodaniDat	2007
http://linked.open...aciTvurceVysledku	Smékal, Zdeněk Kameníček, Jiří Šindelář, Zdeněk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Univerzita Palackého v Olomouci / Přírodovědecká fakulta
http://linked.open...dnocenehoVysledku	503633
http://linked.open...ai/riv/idVysledku	RIV/61989592:15310/06:00002648
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	palladium(II); platinum(II); cyano-bridged complexes (en)
http://linked.open.../riv/klicoveSlovo	cyano-bridged complexes palladium(II) platinum(II)
http://linked.open...odStatuVydavatele	CZ - Česká republika
http://linked.open...ontrolniKodProRIV	[D4C80A6D286A]
http://linked.open...i/riv/nazevZdroje	Acta Universitatis Palackianae Olomucensis, Facultas Rerum Naturalium, Chemica
http://linked.open...in/vavai/riv/obor	CA
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Polynuclear complexes of elements of iron triad and cooper with cyanide bridges - their structure and magnetic properties
http://linked.open...UplatneniVysledku	2006
http://linked.open...v/svazekPeriodika	45
http://linked.open...iv/tvurceVysledku	Smékal, Zdeněk Kameníček, Jiří Šindelář, Zdeněk Kutláková, Kateřina
issn	0232-0061
number of pages	9 (xsd:int)
http://localhost/t...ganizacniJednotka	15310

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