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  • The octanol-water partition coefficients of seven anthocyanins (in neutral form, pH = 7.0) were measured by means of MEKC. A new iterative method for the estimation of migration time of electroosmotic flow (EOF) and micelles in MEKC is presented. This calculation is based on Gauss-Newton linearization of the dependence between migration indices and migration times of a set of suitable standards and the application of an advanced statistical evaluation procedure. The values of partition coefficients obtained with the aid of an iterative process are compared with values obtained on use of EOF and micelle markers.
  • The octanol-water partition coefficients of seven anthocyanins (in neutral form, pH = 7.0) were measured by means of MEKC. A new iterative method for the estimation of migration time of electroosmotic flow (EOF) and micelles in MEKC is presented. This calculation is based on Gauss-Newton linearization of the dependence between migration indices and migration times of a set of suitable standards and the application of an advanced statistical evaluation procedure. The values of partition coefficients obtained with the aid of an iterative process are compared with values obtained on use of EOF and micelle markers. (en)
  • Je diskutován odhad rozdělovacích koeficientů pomocí MEKC. Druhá část je věnována antokyaninům. (cs)
Title
  • Estimation of partition coefficients by MEKC - Part 2: Anthocyanins
  • Estimation of partition coefficients by MEKC - Part 2: Anthocyanins (en)
  • Odhad rozdělovacích koeficientů pomocí MEKC - část 2: antokyaniny (cs)
skos:prefLabel
  • Estimation of partition coefficients by MEKC - Part 2: Anthocyanins
  • Estimation of partition coefficients by MEKC - Part 2: Anthocyanins (en)
  • Odhad rozdělovacích koeficientů pomocí MEKC - část 2: antokyaniny (cs)
skos:notation
  • RIV/61989592:15310/05:00001894!RIV06-MSM-15310___
http://linked.open.../vavai/riv/strany
  • 1285-1290
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GP203/02/D013), Z(MSM6198959216)
http://linked.open...iv/cisloPeriodika
  • 12
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 520561
http://linked.open...ai/riv/idVysledku
  • RIV/61989592:15310/05:00001894
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • ELECTROKINETIC CAPILLARY CHROMATOGRAPHY; ATOMIC PHYSICOCHEMICAL PARAMETERS; DIRECTED QUANTITATIVE STRUCTURE; LIQUID-CHROMATOGRAPHY; INDEX; WATER (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [61AE09FC6C8B]
http://linked.open...i/riv/nazevZdroje
  • Journal of Separation Science
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 28
http://linked.open...iv/tvurceVysledku
  • Barták, Petr
  • Bednář, Petr
  • Lemr, Karel
  • Ševčík, Juraj
  • Müller, L.
http://linked.open...n/vavai/riv/zamer
issn
  • 1615-9306
number of pages
http://localhost/t...ganizacniJednotka
  • 15310
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