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rdf:type
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Description
| - A Ni(II) dithiocarbamates with the tridentate P,P,P-ligand of composition [Ni(pe2dtc)(triphosI)]X (triphos = C34H33P3 = bis(2-diphenylphoshinoethyl)phenylphosphine, pe2dtc =dipentyldithiocarbamate, X = Cl, PF6, ClO4), [Ni(bz2dtc)(triphosI)]X (bz2dtc = dibenzyldithiocarbamate, X = Cl, PF6, BPh4, ClO4) have been synthesized and studied by thermal analysis, IR and UV/VIS spectroscopy, P31{H1} NMR spectroscopy, magnetochemical and conductivity measurements. All complexes are diamagnetic, 1:1 electrolytes. X-ray structural analysis was solved for the [Ni(pe2dtc)(triphosI)]PF6 and [Ni(bz2dtc)(triphosI)]PF6; the presence of NiS2P3 chromophore with penta-coordinated central atom was confirmed.
- A Ni(II) dithiocarbamates with the tridentate P,P,P-ligand of composition [Ni(pe2dtc)(triphosI)]X (triphos = C34H33P3 = bis(2-diphenylphoshinoethyl)phenylphosphine, pe2dtc =dipentyldithiocarbamate, X = Cl, PF6, ClO4), [Ni(bz2dtc)(triphosI)]X (bz2dtc = dibenzyldithiocarbamate, X = Cl, PF6, BPh4, ClO4) have been synthesized and studied by thermal analysis, IR and UV/VIS spectroscopy, P31{H1} NMR spectroscopy, magnetochemical and conductivity measurements. All complexes are diamagnetic, 1:1 electrolytes. X-ray structural analysis was solved for the [Ni(pe2dtc)(triphosI)]PF6 and [Ni(bz2dtc)(triphosI)]PF6; the presence of NiS2P3 chromophore with penta-coordinated central atom was confirmed. (en)
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Title
| - Nickel(II) dithiocarbamates with bis(2-diphenylphosphinoethyl)phenylphosphine
- Nickel(II) dithiocarbamates with bis(2-diphenylphosphinoethyl)phenylphosphine (en)
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skos:prefLabel
| - Nickel(II) dithiocarbamates with bis(2-diphenylphosphinoethyl)phenylphosphine
- Nickel(II) dithiocarbamates with bis(2-diphenylphosphinoethyl)phenylphosphine (en)
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skos:notation
| - RIV/61989592:15310/04:00009889!RIV10-MSM-15310___
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61989592:15310/04:00009889
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - crystal structure determination; phosphorus-donor ligands; pyrrolidinedithiocarbamate complexes; chelating phosphines; NiS2P2 chromophore (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Polish Journal of Chemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Cvek, Boris
- Maloň, Michal
- Pastorek, Richard
- Kameníček, Jiří
- Pavlíček, Marek
- Husárek, Josef
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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http://localhost/t...ganizacniJednotka
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