About: Nickel(II) dithiocarbamates with bis(2-diphenylphosphinoethyl)phenylphosphine     Goto   Sponge   NotDistinct   Permalink

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  • A Ni(II) dithiocarbamates with the tridentate P,P,P-ligand of composition [Ni(pe2dtc)(triphosI)]X (triphos = C34H33P3 = bis(2-diphenylphoshinoethyl)phenylphosphine, pe2dtc =dipentyldithiocarbamate, X = Cl, PF6, ClO4), [Ni(bz2dtc)(triphosI)]X (bz2dtc = dibenzyldithiocarbamate, X = Cl, PF6, BPh4, ClO4) have been synthesized and studied by thermal analysis, IR and UV/VIS spectroscopy, P31{H1} NMR spectroscopy, magnetochemical and conductivity measurements. All complexes are diamagnetic, 1:1 electrolytes. X-ray structural analysis was solved for the [Ni(pe2dtc)(triphosI)]PF6 and [Ni(bz2dtc)(triphosI)]PF6; the presence of NiS2P3 chromophore with penta-coordinated central atom was confirmed.
  • A Ni(II) dithiocarbamates with the tridentate P,P,P-ligand of composition [Ni(pe2dtc)(triphosI)]X (triphos = C34H33P3 = bis(2-diphenylphoshinoethyl)phenylphosphine, pe2dtc =dipentyldithiocarbamate, X = Cl, PF6, ClO4), [Ni(bz2dtc)(triphosI)]X (bz2dtc = dibenzyldithiocarbamate, X = Cl, PF6, BPh4, ClO4) have been synthesized and studied by thermal analysis, IR and UV/VIS spectroscopy, P31{H1} NMR spectroscopy, magnetochemical and conductivity measurements. All complexes are diamagnetic, 1:1 electrolytes. X-ray structural analysis was solved for the [Ni(pe2dtc)(triphosI)]PF6 and [Ni(bz2dtc)(triphosI)]PF6; the presence of NiS2P3 chromophore with penta-coordinated central atom was confirmed. (en)
Title
  • Nickel(II) dithiocarbamates with bis(2-diphenylphosphinoethyl)phenylphosphine
  • Nickel(II) dithiocarbamates with bis(2-diphenylphosphinoethyl)phenylphosphine (en)
skos:prefLabel
  • Nickel(II) dithiocarbamates with bis(2-diphenylphosphinoethyl)phenylphosphine
  • Nickel(II) dithiocarbamates with bis(2-diphenylphosphinoethyl)phenylphosphine (en)
skos:notation
  • RIV/61989592:15310/04:00009889!RIV10-MSM-15310___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(MSM 153100007)
http://linked.open...iv/cisloPeriodika
  • 5
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 576264
http://linked.open...ai/riv/idVysledku
  • RIV/61989592:15310/04:00009889
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • crystal structure determination; phosphorus-donor ligands; pyrrolidinedithiocarbamate complexes; chelating phosphines; NiS2P2 chromophore (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • PL - Polská republika
http://linked.open...ontrolniKodProRIV
  • [89B0D80790C1]
http://linked.open...i/riv/nazevZdroje
  • Polish Journal of Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 78
http://linked.open...iv/tvurceVysledku
  • Cvek, Boris
  • Maloň, Michal
  • Pastorek, Richard
  • Kameníček, Jiří
  • Pavlíček, Marek
  • Husárek, Josef
http://linked.open...n/vavai/riv/zamer
issn
  • 0137-5083
number of pages
http://localhost/t...ganizacniJednotka
  • 15310
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