About: Effects of partial/asymmetrical filling of micelles and chiral selectors on capillary electrophoresis enantiomeric separation: Generation of a gradient     Goto   Sponge   NotDistinct   Permalink

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Description
  • Práce popisuje efekty částečného nesymetrického zaplňování micel a chirálních selektorů při enentiometerické separaci v kapilární elektroforéze: generování gradientu. (cs)
  • The effect of several experimental parameters on enantiomeric separations in micellar capillary electrophoresis (MCE) was studied. A model separation system was tested. It was composed of an acidic phosphate buffer with sodium dodecyl sulfate (SDS) and hydroxypropyl-beta-cyclodextrin (HP-beta-CD) as the chiral selector. A substituted angelicin was used as a chiral analyte. Changes in the concentration of SDS micelles/SDS monomers in the presence of HP-beta-CD and their impact on the enantioselective separation were investigated. Variation of the composition of electrolytes in the individual compartments of the separation system (inlet vial, capillary, and outlet vial) affected both the migration times and the resolution of the enantiomers. Current vs. time dependencies also were monitored during the separations. A mathematical model of electromigration in micellar systems with chiral selector present was proposed and a computer simulation was used to explain the observed phenomena and to confirm the g
  • The effect of several experimental parameters on enantiomeric separations in micellar capillary electrophoresis (MCE) was studied. A model separation system was tested. It was composed of an acidic phosphate buffer with sodium dodecyl sulfate (SDS) and hydroxypropyl-beta-cyclodextrin (HP-beta-CD) as the chiral selector. A substituted angelicin was used as a chiral analyte. Changes in the concentration of SDS micelles/SDS monomers in the presence of HP-beta-CD and their impact on the enantioselective separation were investigated. Variation of the composition of electrolytes in the individual compartments of the separation system (inlet vial, capillary, and outlet vial) affected both the migration times and the resolution of the enantiomers. Current vs. time dependencies also were monitored during the separations. A mathematical model of electromigration in micellar systems with chiral selector present was proposed and a computer simulation was used to explain the observed phenomena and to confirm the g (en)
Title
  • Efekty částečného nesymetrického zaplňování micel a chirálních selektorů při enentiometerické separaci v kapilární elektroforéze: generování gradientu (cs)
  • Effects of partial/asymmetrical filling of micelles and chiral selectors on capillary electrophoresis enantiomeric separation: Generation of a gradient
  • Effects of partial/asymmetrical filling of micelles and chiral selectors on capillary electrophoresis enantiomeric separation: Generation of a gradient (en)
skos:prefLabel
  • Efekty částečného nesymetrického zaplňování micel a chirálních selektorů při enentiometerické separaci v kapilární elektroforéze: generování gradientu (cs)
  • Effects of partial/asymmetrical filling of micelles and chiral selectors on capillary electrophoresis enantiomeric separation: Generation of a gradient
  • Effects of partial/asymmetrical filling of micelles and chiral selectors on capillary electrophoresis enantiomeric separation: Generation of a gradient (en)
skos:notation
  • RIV/61989592:15310/04:00002289!RIV/2005/GA0/153105/N
http://linked.open.../vavai/riv/strany
  • 2693-2700
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/03/0161), Z(MSM 153100013)
http://linked.open...iv/cisloPeriodika
  • 16
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 562187
http://linked.open...ai/riv/idVysledku
  • RIV/61989592:15310/04:00002289
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • cyclodextrin;enantioselective micellar electrokinetic chromatography;sodium dodecyl sulfate (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [4CCB3F3DC34F]
http://linked.open...i/riv/nazevZdroje
  • Electrophoresis
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 25
http://linked.open...iv/tvurceVysledku
  • Armstrong, D. W.
  • Tesařová, Eva
  • Ševčík, Juraj
http://linked.open...n/vavai/riv/zamer
issn
  • 0173-0835
number of pages
http://localhost/t...ganizacniJednotka
  • 15310
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